Journal of the Chemical Society, Volume 75

Front Cover
Chemical Society., 1899
 

Contents

Preparation of Pure Alkali Nitrites
85
by Sodium or Potassium By EDWARD DIVERS M D
95
Derivatives of Camphoric Acid Part III By FRED
125
aKetotetrahydronaphthalene By FREDERIC STANLEY
144
Production of Optically Active Mono and Dialkyl
153
Determination of the Constitution of Fatty Acids
161
1
164
Some Halogen Derivatives of Acetone Dicarboxylic
169
11
171
Oxidation of Sulphocamphylic Acid By W H PERKIN
175
36
187
Researches on Moorland Waters I Acidity
196
An Isomeride of Amarine By H LLOYD SNAPE D Sc
208
61
239
The Action of Ammonia on Ethereal Salts of Organic
245
66
253
The Changes of Volume due to Dilution of Aqueous
254
72
262
Methanetrisulphonic Acid By ERNEST HAROLD
278
Attempts to Prepare Pure Starch Derivatives through
308
The Stable Dextrin of Starch Transformations
315
Position Isomerism and Optical Activity
337
Some Regularities in the Rotatory Power of Homo
347
245
361
Detection and Determination of Sucrose in
371
Action of Metallic Thiocyanates on Certain Sub
388
Formation of aPyrone Compounds and their Trans
411
XLHydrolysis of the yCyanides of Disubstituted Aceto
417
Bromomethylfurfuraldehyde By HENRY J HORSTMAN
423
A Reaction of some Phenolic Colouring Matters
433
A Method of Studying Polymorphism and on Poly
455
Contribution to the Characterisation of Racemic
465
The Rotatory Powers of Optically Active Methoxy
483
PositionIsomerism and Optical Activity The Com
493
Synthesis of some Derivatives of BBDipyridyl from
507
The Condensation of Oxalic Acid and Resorcinol By JOHN
518
Ethyl Ammoniumsulphite By EDWARD DIVERS
533
The Action of Certain Acidic Oxides on Salts of Hydroxy
542
Derivatives of aaDibromocamphorsulphonic Acid
558
A New Compound of Arsenic and Tellurium By E C
597
The Action of Nitric Oxide on Nitrogen Peroxide
613
On the Mode of Burning of Carbon By HAROLD BAILY
630
LXIIA Study of the Absorption Spectra of Isatin Car
640
Preparation of Acid Phenylic Salts of Dibasic Acids
661
Condensation of Ethylic Salts of Acids of
778
Action of Hydrogen Peroxide on Carbohydrates in
786
The Action of Alkyl Haloids on Hydroxylamine
792
The Condensation of Ethylic Acetonedicarboxylate
808
The Colouring Matter of Cotton Flowers Gossypium
825
Researches on the Alkylsubstituted Succinic Acids
839
Some Derivatives of Dibenzyl Ketone By FRANCIS
865
Action of Light and of Oxygen on Dibenzyl Ketone
871
The Composition and Tensions of Dissociation
883
The AluminiumMercury Couple Part II
893
The cis and transBPhenylbutaneaa₁₂tricarb
904
The Action of Ethylene Dibromide and Trimethylene
921
Influence of Substitution on Specific Rotation in
934
Studies of the Acids of the Acetylene Series
954
XCIIIA Contribution to the Chemistry of the Mandelic Acids
964
786
968
Nonexistence of the socalled Suboxide of Phosphorus
973
The Chlorine Derivatives of Pyridine Part III
979
Homocamphoronic
986
792
1004
Amidoamidines of the Naphthalene Series
1011
Condensations of Anhydracetonebenzil and its Ana
1017
Triphenyloxazolone By FRANCIS R JAPP F R S
1027
Furfuran Derivatives from Benzoin and Phenols
1035
Interaction of Benzoin with Phenylenediamines
1043
Synthetical Preparation of Glucosides By HUGH RYAN
1054
On a Method for Providing a Current of Gaseous
1060
The Application of Powerful Optically Active Acids
1066
The Application of Powerful Optically Active Acids
1093
The Application of Powerful Optically Active Acids
1105
A Method for Discriminating between Nonracemic
1111
The Characterisation of Racemic Liquids
1119
Asymmetric Optically Active Nitrogen Compounds
1127
Action of Hydrolytic Agents on aDibromocamphor
1134
Camphoroxime Part III Behaviour of Camphor
1141
Influence of an Unsaturated Linking on the Optical
1149
The Interaction of Sodium Hydroxide and Benz
1155
The Ultraviolet Absorption Spectrum of Proteids
1162
its OxidationProducts and Constitution
1181
808
1184
1134
1195
1060
1196
11141
1208

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Page 679 - In choosing or constructing a still-head, the first point to be considered is its efficiency in separating the components of a mixture. It frequently happens, however, that the quantity of liquid available is small and, in any case, when a series of fractional distillations has to be carried out, some of the fractions eventually become very small : in 'such a case, of two still-heads of equal efficiency, that one is the more useful which allows of the distillation of the smaller quantity of liquid....
Page 1006 - As(C2H5)1Cl.4H'0, which dissolve readily in water and alcohol, but are insoluble in ether. The aqueous solution immediately precipitates chloride of silver from the nitrate and forms an insoluble double salt with mercuric Morirle.
Page 703 - The weight of liquid and vapour in the still-head was more than twice as great as in those of Glinsky or Young and Thomas. 4. Flow of Liquid through the Reflux Tubes. — It is of the utmost importance that there should be a rapid flow of condensed liquid through the reflux tubes, especially if they- are outside the main tube and are not heated by the ascending vapour. To take an extreme case, suppose that there were no back flow at all through the reflux tubes and that the traps simply became filled...
Page 106 - ... published, show that nitric oxide may serve as a carrier of atmospheric oxygen to silver nitrite ; and it is therefore most probable that in this case also some of the nitric oxide liberated serves to carry a little oxygen to the still undecomposed new silver-salt. During its decomposition by heat it does not fuse or exhibit any other change except that from a bright yellow to a silver-white colour. After a red heat nothing remains but pure silver. 5. The following determinations of the amount...
Page 536 - ... dissolved in nitric acid, the solution evaporated to dryness, and the residue repeatedly moistened with water and dried again by heat.
Page 828 - Ginster, Ger.) is found in the pastures, thickets, and waste places throughout Central and Southern Europe, across Russian Asia to the Baikal, and northward to Southern Sweden. It is frequent in the greater part of England, but rare in Ireland and Scotland. The fact that it contains a yellow colouring matter is recorded by numerous writers, and the following embody the principal references to the dyeing and general properties of the plant : Bancroft (Philosophy of Permanent Colours...
Page 693 - B, of 7-5 to 8 mm. internal diameter and 60 mm. long, open at each end and widened below into the form of a funnel which rests on the constricted part of A and...
Page 693 - The whole of the liquid condensed in the still-head above any section collects together and flows down the walls until it falls in drops from the depression, E, into the funnel. From this it falls on to the top of the middle tube and spreads itself over its surface, falling again in drops from the bottom of this tube, and finally passing between the bottom of the inner tube and the constriction in the outer one on which the inner tube rests, and thus into the section below. There is no...
Page 697 - The upper and wider part of the reflux tube has an internal diameter of 4'5 mm., the narrow, U-shaped part, which serves as a trap, an internal diameter of 3 mm. ; if, however, the number of constrictions exceeds 10 or 12, the traps for the lower reflux tubes should be slightly wider, say 3 '5 mm.
Page 59 - This research was carried out with the aid of a grant from the United States Public Health Service. The authors are grateful to Professor Ray D. Owen, of the Biology Division of this Institute, for his helpful suggestions.

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