Quarterly Journal of the Chemical Society of London, Volume 6 |
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Page 1668
... chloride was purified by Mohammad and Satchell's method.4 AnalaR antimony trichloride was sublimed . It had m.p. 72-73 ° . Stannic chloride was purified as before.1 Trichlorophenyltin was prepared by Luijten and van Der Kerk's method ...
... chloride was purified by Mohammad and Satchell's method.4 AnalaR antimony trichloride was sublimed . It had m.p. 72-73 ° . Stannic chloride was purified as before.1 Trichlorophenyltin was prepared by Luijten and van Der Kerk's method ...
Page 1671
... chloride , however , has to compete with the ether for the stannic chloride . As a general rule even those metal halide - acetyl chloride adducts that are stable in the solid state dissociate in solvents such as nitrobenzene.10 ...
... chloride , however , has to compete with the ether for the stannic chloride . As a general rule even those metal halide - acetyl chloride adducts that are stable in the solid state dissociate in solvents such as nitrobenzene.10 ...
Page 1672
... Chloride - catalysed Reaction . - The rate equa- tion ( 4 ) has the same form as that for the stannic chloride reaction [ equation ( 1 ) ] . It is therefore probable that the reaction mechanisms for the two catalysts are the same ...
... Chloride - catalysed Reaction . - The rate equa- tion ( 4 ) has the same form as that for the stannic chloride reaction [ equation ( 1 ) ] . It is therefore probable that the reaction mechanisms for the two catalysts are the same ...
Contents
ISOWA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite adducts alcohol aluminium hydride Amer amines aqueous aromatic atom attack bands benzene benzophenones benzyl bond calculated carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydrogen hydrolysis hydroxide hydroxyl interaction ionic strength isomer k₁ k₂ ketone kinetic leaving group measured mechanism methyl methyl phosphate mixture molar Kerr constants mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plots polarisability proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity rearrangement reduction ring rotation similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure substituent sulphate radical anion Table temperature tetraphenylallene thiophen titanium(III values Δε ΣΔε/Σω