Quarterly Journal of the Chemical Society of London, Volume 6 |
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Page 1092
... electron from carboxylate anions , as shown by the formation of the methyl and ethyl radicals , respectively , by oxidation of acetate and propionate anions . In this respect it differs , at least in degree , from the hydroxyl radical ...
... electron from carboxylate anions , as shown by the formation of the methyl and ethyl radicals , respectively , by oxidation of acetate and propionate anions . In this respect it differs , at least in degree , from the hydroxyl radical ...
Page 1483
... electron in methanol 5a , and n - propanol containing 2-3 % ( v / v ) of water.5c In pure ice the mobile electron reacts chemically rather than becoming trapped , but in alkaline ice the electron is trapped . At low alkali ...
... electron in methanol 5a , and n - propanol containing 2-3 % ( v / v ) of water.5c In pure ice the mobile electron reacts chemically rather than becoming trapped , but in alkaline ice the electron is trapped . At low alkali ...
Page 1556
... electron density at the carbonyl group.1 In this work , which shows that this and related stretching fre- quencies may also be of value in determining the absolute electron density in functional groups of free radicals , the ketyls of ...
... electron density at the carbonyl group.1 In this work , which shows that this and related stretching fre- quencies may also be of value in determining the absolute electron density in functional groups of free radicals , the ketyls of ...
Contents
ISOWA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite adducts alcohol aluminium hydride Amer amines aqueous aromatic atom attack bands benzene benzophenones benzyl bond calculated carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydrogen hydrolysis hydroxide hydroxyl interaction ionic strength isomer k₁ k₂ ketone kinetic leaving group measured mechanism methyl methyl phosphate mixture molar Kerr constants mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plots polarisability proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity rearrangement reduction ring rotation similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure substituent sulphate radical anion Table temperature tetraphenylallene thiophen titanium(III values Δε ΣΔε/Σω