Quarterly Journal of the Chemical Society of London, Volume 6 |
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Page 1311
... ester and metal ion ( Table 1 , Figure 1 ) . The rate equation therefore takes the form ( 10 ) . Values of k1 , the second - order rate -d [ Ester ] / dt = k1 [ Hg2 + ] [ Ester ] ( 10 ) ( 11 ) constant , are in Table 3 . = Robs [ Ester ] ...
... ester and metal ion ( Table 1 , Figure 1 ) . The rate equation therefore takes the form ( 10 ) . Values of k1 , the second - order rate -d [ Ester ] / dt = k1 [ Hg2 + ] [ Ester ] ( 10 ) ( 11 ) constant , are in Table 3 . = Robs [ Ester ] ...
Page 1323
... Ester , 2 - Acetylphenyl Mesitoate : Acetal Formation under Basic Conditions as a Mechanistic Consequence of such Participation 1 By Hugh D. Burrows and R. Malcolm Topping , * School of Molecular Sciences , University of Sussex ...
... Ester , 2 - Acetylphenyl Mesitoate : Acetal Formation under Basic Conditions as a Mechanistic Consequence of such Participation 1 By Hugh D. Burrows and R. Malcolm Topping , * School of Molecular Sciences , University of Sussex ...
Page 1327
... ester carbonyl group is much more likely with the unhindered ester ( X ) than with the ester ( IV ) and an estimate of such incursion was gained by repeating the above reaction under nonaqueous con- ditions . Under such conditions [ ester ...
... ester carbonyl group is much more likely with the unhindered ester ( X ) than with the ester ( IV ) and an estimate of such incursion was gained by repeating the above reaction under nonaqueous con- ditions . Under such conditions [ ester ...
Contents
ISCHA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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absorption acetic acid activation added addition alcohol Amer amine anhydrosulphite anion appears aqueous aromatic assigned atom attack bands base benzene bond buffer calculated carbon carbon tetrachloride Chem chloride compared compounds concentration conformation containing corresponding decomposition derived described determined discussed effect electron energy equation ester ether evidence excess expected experimental experiments factors Figure followed formation formed further gave give given hydrogen hydrolysis increase indicate interaction involving kinetic less measured mechanism method methyl MICHIGAN mixture molecular molecules nitrogen nucleophilic observed obtained occurs organic oxidation phenyl phosphate plot position possible prepared presence proton pyridine radical radical anion rate constants ratio reaction reactivity reduction relative reported requires respectively ring showed shown similar sodium solution solvent spectra spectrum splitting structure studied substituent suggested Table temperature transition University values yield