Quarterly Journal of the Chemical Society of London, Volume 6 |
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Results 1-3 of 81
Page 1114
... Excess volume ( ml./mole ) 2.0 1.2 20 40 60 Tetraphenylallene ( moles % ) O 80 100 FIGURE 1 Excess volumes of mixing for the tetraphenylallene- pyrene system at A , 136-8 ° ; O , 166.8 ° ; and , 196.8 ° mixture , and the solids obtained ...
... Excess volume ( ml./mole ) 2.0 1.2 20 40 60 Tetraphenylallene ( moles % ) O 80 100 FIGURE 1 Excess volumes of mixing for the tetraphenylallene- pyrene system at A , 136-8 ° ; O , 166.8 ° ; and , 196.8 ° mixture , and the solids obtained ...
Page 1407
... excess of acetic acid over ( II ) and also showed a linear variation with [ DOAc ] up to ca. 7 mol excess of deuterio- acetic acid over ( II ) [ Tables 5 ( b ) and ( c ) , and equations ( 1 ) - ( 4 ) ] . However , beyond 4 mol excess of ...
... excess of acetic acid over ( II ) and also showed a linear variation with [ DOAc ] up to ca. 7 mol excess of deuterio- acetic acid over ( II ) [ Tables 5 ( b ) and ( c ) , and equations ( 1 ) - ( 4 ) ] . However , beyond 4 mol excess of ...
Page 1461
... excess free unity ( e.g. , for the n - CH14 - phosphate system , in the ln x , = B1 + Cu Bij Cij T ( 5 ) energy of mixing of component 1 is given by equation ~ x ( 2 ) one has equation ( 9 ) . Equation ( 9 ) differs E RT In y , ( 2 ) ...
... excess free unity ( e.g. , for the n - CH14 - phosphate system , in the ln x , = B1 + Cu Bij Cij T ( 5 ) energy of mixing of component 1 is given by equation ~ x ( 2 ) one has equation ( 9 ) . Equation ( 9 ) differs E RT In y , ( 2 ) ...
Contents
ISOWA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite adducts alcohol aluminium hydride Amer amines aqueous aromatic atom attack bands benzene benzophenones benzyl bond calculated carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydrogen hydrolysis hydroxide hydroxyl interaction ionic strength isomer k₁ k₂ ketone kinetic leaving group measured mechanism methyl methyl phosphate mixture molar Kerr constants mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plots polarisability proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity rearrangement reduction ring rotation similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure substituent sulphate radical anion Table temperature tetraphenylallene thiophen titanium(III values Δε ΣΔε/Σω