Quarterly Journal of the Chemical Society of London, Volume 6 |
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Results 1-3 of 84
Page 1373
... further oxidation of the radicals to give [ RH ] + . Further , since all of these are odd alternant species the potentials for oxidation of the radicals should be near + 0 · 4 V. When the -carbanions had been detected in the reduction ...
... further oxidation of the radicals to give [ RH ] + . Further , since all of these are odd alternant species the potentials for oxidation of the radicals should be near + 0 · 4 V. When the -carbanions had been detected in the reduction ...
Page 1380
... further fine splitting , 3 - H ) , 6.95 ( 1H , t , with further fine splitting , 2 - H ) , 4.7 ( 1H , d , with further fine splitting , 1 - H ) . G.1.c. ( B ) showed that the initial mixture contained 68 % of the trans , trans- and 32 ...
... further fine splitting , 3 - H ) , 6.95 ( 1H , t , with further fine splitting , 2 - H ) , 4.7 ( 1H , d , with further fine splitting , 1 - H ) . G.1.c. ( B ) showed that the initial mixture contained 68 % of the trans , trans- and 32 ...
Page 1560
... further with a range of benzo - substituted fluorenes . It was hoped to obtain further information on the nature of decay mechanism . EXPERIMENTAL All operations were performed with standard high- vacuum techniques . described.5 ...
... further with a range of benzo - substituted fluorenes . It was hoped to obtain further information on the nature of decay mechanism . EXPERIMENTAL All operations were performed with standard high- vacuum techniques . described.5 ...
Contents
ISOWA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite adducts alcohol aluminium hydride Amer amines aqueous aromatic atom attack bands benzene benzophenones benzyl bond calculated carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydrogen hydrolysis hydroxide hydroxyl interaction ionic strength isomer k₁ k₂ ketone kinetic leaving group measured mechanism methyl methyl phosphate mixture molar Kerr constants mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plots polarisability proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity rearrangement reduction ring rotation similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure substituent sulphate radical anion Table temperature tetraphenylallene thiophen titanium(III values Δε ΣΔε/Σω