Quarterly Journal of the Chemical Society of London, Volume 6 |
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Results 1-3 of 84
Page 1079
... radical ( IX ) ; this reaction is analogous to the formation of the acetonyl radical by the oxidation of 1 - chloropropan - 2 - ol with the hydroxyl radical , which is considered to occur according to reaction ( 9 ) .29 Moreover , the ...
... radical ( IX ) ; this reaction is analogous to the formation of the acetonyl radical by the oxidation of 1 - chloropropan - 2 - ol with the hydroxyl radical , which is considered to occur according to reaction ( 9 ) .29 Moreover , the ...
Page 1081
... radical CMe , NO , with the radical ⚫CMe , OH or CMe , OCH Me , as reducing agent is then accounted for by the hypothesis that the derived carbonium ions are stable enough to diffuse away from the chloronitroalkane radical anion , this ...
... radical CMe , NO , with the radical ⚫CMe , OH or CMe , OCH Me , as reducing agent is then accounted for by the hypothesis that the derived carbonium ions are stable enough to diffuse away from the chloronitroalkane radical anion , this ...
Page 1085
... radical anion ( III ) and the latter the radical anion ( IV ) . In accord with this view , alteration of the pH to 10 or to 8 resulted in an increase or a decrease , respectively , in the ratio of the observed concentrations of the ...
... radical anion ( III ) and the latter the radical anion ( IV ) . In accord with this view , alteration of the pH to 10 or to 8 resulted in an increase or a decrease , respectively , in the ratio of the observed concentrations of the ...
Contents
ISCHA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite addition adducts alcohol Amer amine aqueous aromatic ation atom attack bands benzene benzyl bond buffer calculated carbon carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition derived dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation formed hydride hydrogen hydrolysis hydroxide hydroxyl interaction isomer k₁ k₂ kinetic leaving group measured mechanism methyl mixture molar mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plot proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity reduction ring rotation showed similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure studied substituent sulphate radical anion sulphur Table temperature thiophen titanium(III values yield ΣΔε/Σω