Quarterly Journal of the Chemical Society of London, Volume 6 |
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Page 1048
... rate constants of the initiation and propagation steps of the hydroxyl- initiated process , and the effect of dielectric constant on the rate constants . In addition , the value of ( k1 + k [ OH ] ) ь / ( k1 ) n ( which is simply the ...
... rate constants of the initiation and propagation steps of the hydroxyl- initiated process , and the effect of dielectric constant on the rate constants . In addition , the value of ( k1 + k [ OH ] ) ь / ( k1 ) n ( which is simply the ...
Page 1056
... rates of the pyridine - catalysed hydrolysis of benzenesulphonyl chloride have been reported.1 The results were consistent with a nucleophilic catalysis mechanism with the rate constants for pyridine attack linearly related to the pKa ...
... rates of the pyridine - catalysed hydrolysis of benzenesulphonyl chloride have been reported.1 The results were consistent with a nucleophilic catalysis mechanism with the rate constants for pyridine attack linearly related to the pKa ...
Page 1174
... rate constant for acetate decreases with increasing acetic acid ... constants for spontaneous hydrolysis of 2 - aryloxy- 2 - oxo - 1,3,2 ... rate constants for hydrolysis against buffer concentration , to zero buffer concentration ...
... rate constant for acetate decreases with increasing acetic acid ... constants for spontaneous hydrolysis of 2 - aryloxy- 2 - oxo - 1,3,2 ... rate constants for hydrolysis against buffer concentration , to zero buffer concentration ...
Contents
ISOWA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite adducts alcohol aluminium hydride Amer amines aqueous aromatic atom attack bands benzene benzophenones benzyl bond calculated carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydrogen hydrolysis hydroxide hydroxyl interaction ionic strength isomer k₁ k₂ ketone kinetic leaving group measured mechanism methyl methyl phosphate mixture molar Kerr constants mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate plots polarisability proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity rearrangement reduction ring rotation similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure substituent sulphate radical anion Table temperature tetraphenylallene thiophen titanium(III values Δε ΣΔε/Σω