Quarterly Journal of the Chemical Society of London, Volume 6 |
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Results 1-3 of 85
Page 1170
... shows no obvious deviation from the line drawn . The point for fluoride is included in Figure 1 and shows that this anion is nearly three orders of magnitude more reactive than an oxyanion of the same basicity ; a difference somewhat ...
... shows no obvious deviation from the line drawn . The point for fluoride is included in Figure 1 and shows that this anion is nearly three orders of magnitude more reactive than an oxyanion of the same basicity ; a difference somewhat ...
Page 1405
... shows a singlet at 8 4.60 p.p.m. in deuteriochloroform . In hexadeuteriobenzene , ( III ) shows a singlet at 8 3.76 p.p.m. and a mixture of ( I ) and ( II ) in hexadeuteriobenzene gave a singlet at 8 3.75 p.p.m. and , in the presence of ...
... shows a singlet at 8 4.60 p.p.m. in deuteriochloroform . In hexadeuteriobenzene , ( III ) shows a singlet at 8 3.76 p.p.m. and a mixture of ( I ) and ( II ) in hexadeuteriobenzene gave a singlet at 8 3.75 p.p.m. and , in the presence of ...
Page 1672
... shows both a first - order and a second - order dependence on aluminium chloride .. The mechanism for the first - order term in aluminium chloride will be analogous to the mechanisms for the stannic chloride- and gallium chloride ...
... shows both a first - order and a second - order dependence on aluminium chloride .. The mechanism for the first - order term in aluminium chloride will be analogous to the mechanisms for the stannic chloride- and gallium chloride ...
Contents
ISCHA 013 | 1034 |
Physical organic chemistry | 1035 |
Studies of the reactions of the anhydrosulphites of ahydroxycarboxylic acids Part IV Steric | 1044 |
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2,4-dinitrophenyl absorption acetic acid aci-anion acid anhydrosulphite addition adducts alcohol Amer amine aqueous aromatic ation atom attack bands benzene benzyl bond buffer calculated carbon carbon tetrachloride carbonyl catalysis Chem chloride compounds concentration conformation corresponding decomposition derived dioxan dipole effect electron electrophilic equation ester ethanol ether ethylene experimental Figure first-order formation hydride hydrogen hydrolysis hydroxide hydroxyl interaction isomer k₁ k₂ kinetic leaving group measured mechanism methyl mixture molar mole mole-¹ molecular molecules nitrogen nitromethane NO₂ nucleophilic observed obtained oxidation oxyanions peroxide persulphate phenyl phenylacetic acid phosphate Phys plot proton pyridine R. J. W. Le Fèvre R. O. C. Norman radical anion rate constants ratio reaction reactivity reduction ring rotation showed similar sodium solution solvent solvolysis spectra spectrum splitting constants steric structure studied substituent sulphate radical anion sulphur Table temperature thiophen titanium(III values yield ΣΔε/Σω