Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2604
... addition of iodomethane to trans - halogenocarbonylbis ( tertiaryphosphine ) rhodium ( 1 ) , trans - RhX ( CO ) ( PR ) , to give , initially , RhXIMe ( CO ) ( PR ) , and finally , the acetyl complex RhXI ( COMe ) ( PR ) 2. Approximate ...
... addition of iodomethane to trans - halogenocarbonylbis ( tertiaryphosphine ) rhodium ( 1 ) , trans - RhX ( CO ) ( PR ) , to give , initially , RhXIMe ( CO ) ( PR ) , and finally , the acetyl complex RhXI ( COMe ) ( PR ) 2. Approximate ...
Page 2729
... addition of halogens or hydrogen halides ( XY ) to [ Rh ( CO ) ( dmpe ) , ] + ( dmpe Me , P.C2HPMe2 ) results in loss of CO to give [ RhXY- ( dmpe ) 2 ] + instead of the expected [ RhX ( CO ) ( dmpe ) 2 ] 2 + 26 From the results ...
... addition of halogens or hydrogen halides ( XY ) to [ Rh ( CO ) ( dmpe ) , ] + ( dmpe Me , P.C2HPMe2 ) results in loss of CO to give [ RhXY- ( dmpe ) 2 ] + instead of the expected [ RhX ( CO ) ( dmpe ) 2 ] 2 + 26 From the results ...
Page 2770
... addition to the aromatic protons , two singlets ( + 6.31 and 6.54 ) for two OCH , groups , and a 1 : 1 doublet ... addition , to give compound ( XI ) , and a trans - addition , to give initially the intermediate ( XII ) which rapidly ...
... addition to the aromatic protons , two singlets ( + 6.31 and 6.54 ) for two OCH , groups , and a 1 : 1 doublet ... addition , to give compound ( XI ) , and a trans - addition , to give initially the intermediate ( XII ) which rapidly ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow