Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2169
... angles are in the range 104-116 ° ( a 1.3 ° ) . The external angles at C ( 4 ) , 109-6 ° and 110-1 ° , indicate that no distortion results from the presence of the axial chlorine substituent . 6 The bond lengths and valency angles ...
... angles are in the range 104-116 ° ( a 1.3 ° ) . The external angles at C ( 4 ) , 109-6 ° and 110-1 ° , indicate that no distortion results from the presence of the axial chlorine substituent . 6 The bond lengths and valency angles ...
Page 2369
... Angles . — Figure 1 shows the experi- mental bond lengths and angles uncorrected for thermal 15 14 105 ( 4 ) 11 1-07 ( 4 ) 106 ( 3 ) 1-236 ( 3 ) 16- 092 ( 5 ) 9 1405 ( 6 ) 8 1441 ( 4 ) 6 : 1357 ( 5 ) 1320 ( 4 ) 5 1-487 ( 4 ) 4 +326 ( 3 ) ...
... Angles . — Figure 1 shows the experi- mental bond lengths and angles uncorrected for thermal 15 14 105 ( 4 ) 11 1-07 ( 4 ) 106 ( 3 ) 1-236 ( 3 ) 16- 092 ( 5 ) 9 1405 ( 6 ) 8 1441 ( 4 ) 6 : 1357 ( 5 ) 1320 ( 4 ) 5 1-487 ( 4 ) 4 +326 ( 3 ) ...
Page 2410
Chemical Society (Great Britain). - distances , bond angles , and torsion angles . A chain of n atoms is then described in terms of n 1 bond distances , n - 2 bond angles , and n - 3 torsion angles ; since these 3n6 internal parameters ...
Chemical Society (Great Britain). - distances , bond angles , and torsion angles . A chain of n atoms is then described in terms of n 1 bond distances , n - 2 bond angles , and n - 3 torsion angles ; since these 3n6 internal parameters ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow