Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2315
... assigned to the most intense band at 15-4 kк . The most intense band in x - polarisation is at 15.9 kк and is assigned as the dyz dz1ya transition . In z - polarisation the dry day transition is electronically allowed and could be assigned ...
... assigned to the most intense band at 15-4 kк . The most intense band in x - polarisation is at 15.9 kк and is assigned as the dyz dz1ya transition . In z - polarisation the dry day transition is electronically allowed and could be assigned ...
Page 2316
... assigned as the dy dy transition occurring with vibronic intensity . This assignment yields the tentative one - electron orbital sequence dr_y2 > dye > drz > dry > da , an order completely different to that obtained in D2 symmetry and ...
... assigned as the dy dy transition occurring with vibronic intensity . This assignment yields the tentative one - electron orbital sequence dr_y2 > dye > drz > dry > da , an order completely different to that obtained in D2 symmetry and ...
Page 3014
... assigned to the 645 and 530 cm . - 1 bands 13 J. Lewis , J. R. Miller , R. L. Richards , and A. Thompson , J. Chem . Soc . , 1965 , 5850 ; E. Kinsella and J. Coward , Spectro- chim . Acta , 1968 , 244 , 2139 . The Partial Anodic ...
... assigned to the 645 and 530 cm . - 1 bands 13 J. Lewis , J. R. Miller , R. L. Richards , and A. Thompson , J. Chem . Soc . , 1965 , 5850 ; E. Kinsella and J. Coward , Spectro- chim . Acta , 1968 , 244 , 2139 . The Partial Anodic ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow