Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2291
... bonds from ortho- gonality such that the ligand bonds cis to the nitrogen atom are bent away from it , and the lengthening of the Re - Cl bond trans to the nitrogen atom in [ ReNCl- ( PEtPh2 ) 3 ] have been attributed to steric factors ...
... bonds from ortho- gonality such that the ligand bonds cis to the nitrogen atom are bent away from it , and the lengthening of the Re - Cl bond trans to the nitrogen atom in [ ReNCl- ( PEtPh2 ) 3 ] have been attributed to steric factors ...
Page 2410
Chemical Society (Great Britain). - distances , bond angles , and torsion angles . A chain of n atoms is then described in terms of n 1 bond distances , n - 2 bond angles , and n - 3 torsion angles ; since these 3n6 internal parameters ...
Chemical Society (Great Britain). - distances , bond angles , and torsion angles . A chain of n atoms is then described in terms of n 1 bond distances , n - 2 bond angles , and n - 3 torsion angles ; since these 3n6 internal parameters ...
Page 2901
... bonds were assumed constant in all the calculations . The following general conclusions are not very sensitive to the choice of parameters for N. 6 = ( a ) The bond orders of the various bonds are N ( 1 ) -C ( 2 ) = 0 · 50 ; C ( 2 ) -N ...
... bonds were assumed constant in all the calculations . The following general conclusions are not very sensitive to the choice of parameters for N. 6 = ( a ) The bond orders of the various bonds are N ( 1 ) -C ( 2 ) = 0 · 50 ; C ( 2 ) -N ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow