Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
From inside the book
Results 1-3 of 85
Page 2344
... co - ordination gives the smallest quadrupole splitting ( A = ca. 0 mm./sec . ) and trigonal bipyramidal co - ordination gives the largest splittings ( A = 2.1-2.6 mm./sec . ) , six - co - ordination . results in small splittings which ...
... co - ordination gives the smallest quadrupole splitting ( A = ca. 0 mm./sec . ) and trigonal bipyramidal co - ordination gives the largest splittings ( A = 2.1-2.6 mm./sec . ) , six - co - ordination . results in small splittings which ...
Page 2464
... co - ordinate through oxygen , as unidentate nitrite- groups in [ Co ( pyridine ) ( ONO ) 2 ] .2 ( pyridine ) , COL ... ordination is suggested for the metal ion in the compounds CoL , ( NO2 ) 2 where L = pyridine or 3 - methylpyridine .
... co - ordinate through oxygen , as unidentate nitrite- groups in [ Co ( pyridine ) ( ONO ) 2 ] .2 ( pyridine ) , COL ... ordination is suggested for the metal ion in the compounds CoL , ( NO2 ) 2 where L = pyridine or 3 - methylpyridine .
Page 2466
... co - ordination geometries are possible for the purple 2 : 1 compounds . Co - ordin- ation of the anions through nitrogen is ruled out on the basis of the i.r. results ( also the high ligand - field strength of nitro - groups would ...
... co - ordination geometries are possible for the purple 2 : 1 compounds . Co - ordin- ation of the anions through nitrogen is ruled out on the basis of the i.r. results ( also the high ligand - field strength of nitro - groups would ...
Other editions - View all
Common terms and phrases
absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow