Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2551
... constant When t = 0 , S = 1 , hence constant = -3 . -- ( 6 ) .. ln ( 1 — X ) -1 — 3 [ 1 − ( 1 − X ) 1 ] = ( 3VDK / Vr2 ) .t ( 7 ) ( b ) C - Kinetics [ Type ( iii ) ] .— The equilibrium equation , in terms of the change in the external ...
... constant When t = 0 , S = 1 , hence constant = -3 . -- ( 6 ) .. ln ( 1 — X ) -1 — 3 [ 1 − ( 1 − X ) 1 ] = ( 3VDK / Vr2 ) .t ( 7 ) ( b ) C - Kinetics [ Type ( iii ) ] .— The equilibrium equation , in terms of the change in the external ...
Page 2630
... constant change in exactly the same way , one obtains the following relations between the conditional constants ẞ ; and the thermodynamic constants Bi * ; B1 ~ B1 * ; B2 ~ ß2 * fx2 ; ßz ~ B3 * ƒx2 ; B4B4 * . For the constants B1 and 84 ...
... constant change in exactly the same way , one obtains the following relations between the conditional constants ẞ ; and the thermodynamic constants Bi * ; B1 ~ B1 * ; B2 ~ ß2 * fx2 ; ßz ~ B3 * ƒx2 ; B4B4 * . For the constants B1 and 84 ...
Page 2672
... constant on the chloride- ion concentration at constant [ H + ] is illustrated in Figure 2 ( a ) and shows a small but definite curvature towards the abscissa . All the above results can be accounted for in terms of a reaction scheme ...
... constant on the chloride- ion concentration at constant [ H + ] is illustrated in Figure 2 ( a ) and shows a small but definite curvature towards the abscissa . All the above results can be accounted for in terms of a reaction scheme ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow