Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2412
... correspond to the same mini- mum of strain - energy . The optimal conformations must then be either congruent or enantiomorphous . In the former case , corresponding to RR or SS con- figuration of the complex as a whole , the two halves ...
... correspond to the same mini- mum of strain - energy . The optimal conformations must then be either congruent or enantiomorphous . In the former case , corresponding to RR or SS con- figuration of the complex as a whole , the two halves ...
Page 2649
... corresponding 3 - picoline , 4 - picoline , and 4 - methoxypyridine complexes . We have extended the method to other pyridine derivatives . The visible absorption spectra of these complexes were similar to each other , as well as to ...
... corresponding 3 - picoline , 4 - picoline , and 4 - methoxypyridine complexes . We have extended the method to other pyridine derivatives . The visible absorption spectra of these complexes were similar to each other , as well as to ...
Page 2847
... corresponding tetracyano- complex under roughly comparable conditions . How- ever , trans - Pt ox , Cl22 is reduced about 5000 times less rapidly than the corresponding cyano - complex . Its rate of reduction is only about 10 times that ...
... corresponding tetracyano- complex under roughly comparable conditions . How- ever , trans - Pt ox , Cl22 is reduced about 5000 times less rapidly than the corresponding cyano - complex . Its rate of reduction is only about 10 times that ...
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Common terms and phrases
absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow