Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2099
... effect of a change in the aryl ligand on the chemical - shifts of the protons in the planar ligand ; ( a ) the transmission of the effect by way of the binding - and -electrons , ( b ) change in the electric dipole of the ( p - XCH1 ) ...
... effect of a change in the aryl ligand on the chemical - shifts of the protons in the planar ligand ; ( a ) the transmission of the effect by way of the binding - and -electrons , ( b ) change in the electric dipole of the ( p - XCH1 ) ...
Page 2100
... effect contributing to the ground - state cis - effect observed in the methine hydrogens between ( p - MeC ̧H1 ) bae Co and ( p - NOCH1 ) bae Co ( and , hence , in the whole series of p - substituted phenyl bae cobalt complexes ) is an ...
... effect contributing to the ground - state cis - effect observed in the methine hydrogens between ( p - MeC ̧H1 ) bae Co and ( p - NOCH1 ) bae Co ( and , hence , in the whole series of p - substituted phenyl bae cobalt complexes ) is an ...
Page 2471
... Effect ' in hexakisaminocyclo- triphosphazatrienes , N , P , R Corr . PK'2.1 value calculated from structural APK ... effect ' . The ' corrected ' pK'.1 presumably represents the value that would be found in the absence of the ...
... Effect ' in hexakisaminocyclo- triphosphazatrienes , N , P , R Corr . PK'2.1 value calculated from structural APK ... effect ' . The ' corrected ' pK'.1 presumably represents the value that would be found in the absence of the ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow