Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2229
... equation ( 3 ) requires the direction of advance- ment to be stipulated as that which is perpendicular to the { 011 } interfaces ; i.e. we must write k cos 0 in equation ( 3 ) , where is defined as in Figure 4 below . Consequently , ...
... equation ( 3 ) requires the direction of advance- ment to be stipulated as that which is perpendicular to the { 011 } interfaces ; i.e. we must write k cos 0 in equation ( 3 ) , where is defined as in Figure 4 below . Consequently , ...
Page 2474
... equations ( 6 ) , ( 9 ) , and ( 11 ) , with aph = 4.2 , gives ar 5.6 , in agreement with equation ( 5 ) . Alternatively , the analysis may be regarded as confirming αph = 4.2 . NCH10 , YR YPh — = pK ' ( VI , corr . ) - pK'a ( VII , corr ...
... equations ( 6 ) , ( 9 ) , and ( 11 ) , with aph = 4.2 , gives ar 5.6 , in agreement with equation ( 5 ) . Alternatively , the analysis may be regarded as confirming αph = 4.2 . NCH10 , YR YPh — = pK ' ( VI , corr . ) - pK'a ( VII , corr ...
Page 2742
... equation ( 14 ) with ex- perimental values ( 1. mole1 sec. ̄1 ) at μ = 1.0 , and values of B1 ( 1. mole1 ) at 25 ° calculated from equation ( 15 ) 45 ° ko ( calc . ) ko ( exp ) × 10-2 × 10-2 25 ° [ Cl ] ( M ) k 。( calc . ) ko ( exp ) ...
... equation ( 14 ) with ex- perimental values ( 1. mole1 sec. ̄1 ) at μ = 1.0 , and values of B1 ( 1. mole1 ) at 25 ° calculated from equation ( 15 ) 45 ° ko ( calc . ) ko ( exp ) × 10-2 × 10-2 25 ° [ Cl ] ( M ) k 。( calc . ) ko ( exp ) ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow