Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2309
... intensity owing to decomposi- tion of the crystal under irradiation . A steady decrease in the intensity of the standard reflexion was observed , amounting to about 30 % at the end of the data collection . The standard deviation of an ...
... intensity owing to decomposi- tion of the crystal under irradiation . A steady decrease in the intensity of the standard reflexion was observed , amounting to about 30 % at the end of the data collection . The standard deviation of an ...
Page 2318
... intensity is in y - polarisation and arises from an in- tensity borrowing process from a low - energy charge- transfer state.18,19 For a day ground state , as in Cu Hoedta ( H2O ) and an electronic mechanism the bulk of the intensity is ...
... intensity is in y - polarisation and arises from an in- tensity borrowing process from a low - energy charge- transfer state.18,19 For a day ground state , as in Cu Hoedta ( H2O ) and an electronic mechanism the bulk of the intensity is ...
Page 2748
... intensity therefore suggest that this property is also controlled by the extent of metal- carbon multiple bonding , at least for the complexes listed in Figure 1 , in agreement with conclusions of Brown and Darensburg.3 35 absence of ...
... intensity therefore suggest that this property is also controlled by the extent of metal- carbon multiple bonding , at least for the complexes listed in Figure 1 , in agreement with conclusions of Brown and Darensburg.3 35 absence of ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow