Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Results 1-3 of 81
Page 2403
... ligand may affect the mechanism of ligand- replacement reactions by promoting an SN2 reaction path . This has been attributed 2 to the ability of the -cyclopentadienyl ligand to remove negative charge from the metal at the moment of ...
... ligand may affect the mechanism of ligand- replacement reactions by promoting an SN2 reaction path . This has been attributed 2 to the ability of the -cyclopentadienyl ligand to remove negative charge from the metal at the moment of ...
Page 2404
... ligand . All the reactions studied , both in tetrahydrofuran and in n - hexane , were first order in molybdenum complex . The first - order rate constants are listed in Tables 2 and 3 , together with rate constants for the reaction of π ...
... ligand . All the reactions studied , both in tetrahydrofuran and in n - hexane , were first order in molybdenum complex . The first - order rate constants are listed in Tables 2 and 3 , together with rate constants for the reaction of π ...
Page 2653
... ligands when the two groups are cis to one another [ Figure ( a ) ] . A ligand trans to the dissociating & ( a ) ( b ) TABLE 4 Summary of kinetic data for the solvolytic aquation and base hydrolysis of some nonionic sulphatobis ...
... ligands when the two groups are cis to one another [ Figure ( a ) ] . A ligand trans to the dissociating & ( a ) ( b ) TABLE 4 Summary of kinetic data for the solvolytic aquation and base hydrolysis of some nonionic sulphatobis ...
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Common terms and phrases
absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow