Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2291
... nitrogen atom also induces an increase in the s - orbital contribution of the nitrogen atom to the o - component of the rhenium - nitrogen bond , which could also account for its slight shortening and apparent strengthening . Our ...
... nitrogen atom also induces an increase in the s - orbital contribution of the nitrogen atom to the o - component of the rhenium - nitrogen bond , which could also account for its slight shortening and apparent strengthening . Our ...
Page 2843
... nitrogen ligand is weaker in both its electron- donor function and its electron - acceptor function than is carbon monoxide in these complexes . This should go a long way to explaining the much lower stability of nitrogen complexes ...
... nitrogen ligand is weaker in both its electron- donor function and its electron - acceptor function than is carbon monoxide in these complexes . This should go a long way to explaining the much lower stability of nitrogen complexes ...
Page 2949
... nitrogen : up to 280 ° Then in air , thermal decomposition occurs followed by oxide transformations : 40 Mn ( CO2 ) 2 280-330 ° MnO3930-950 Mn304 20 % Wt . loss 40 FIGURE 4 Nitrogen B.E.T. specific surface area against % weight loss for ...
... nitrogen : up to 280 ° Then in air , thermal decomposition occurs followed by oxide transformations : 40 Mn ( CO2 ) 2 280-330 ° MnO3930-950 Mn304 20 % Wt . loss 40 FIGURE 4 Nitrogen B.E.T. specific surface area against % weight loss for ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow