Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2262
... obtained from tris - tetrachlorobenzene -. 6 there is only one other titanium complex formally contain- ing titanium ( IV ) and six sulphur donor atoms , namely [ TiSC ( CN ) 12-14 The tetrachlorobenzenedithiolene complex was inert to ...
... obtained from tris - tetrachlorobenzene -. 6 there is only one other titanium complex formally contain- ing titanium ( IV ) and six sulphur donor atoms , namely [ TiSC ( CN ) 12-14 The tetrachlorobenzenedithiolene complex was inert to ...
Page 2623
... Obtained at ca. 20 ° K . Obtained at ca. 140 ° K . • Calculated assuming axial symmetry ( see text ) . d Calculated from the hyperfine tensors found for HCO by scaling them by the ratios of the spin - densities on the appropriate atoms ...
... Obtained at ca. 20 ° K . Obtained at ca. 140 ° K . • Calculated assuming axial symmetry ( see text ) . d Calculated from the hyperfine tensors found for HCO by scaling them by the ratios of the spin - densities on the appropriate atoms ...
Page 2876
... obtained by measuring the heats of solution of the donor , acceptor , and adduct in 2M - hydrochloric acid at 25 ° . The values obtained for – AH , were : InCl3,3py , 39.1 ( 1 ) ; InBг.3py , 41 · 1 ( 4 ) ; Inl ̧ , 3py , 40 · 3 ( 2 ) ...
... obtained by measuring the heats of solution of the donor , acceptor , and adduct in 2M - hydrochloric acid at 25 ° . The values obtained for – AH , were : InCl3,3py , 39.1 ( 1 ) ; InBг.3py , 41 · 1 ( 4 ) ; Inl ̧ , 3py , 40 · 3 ( 2 ) ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow