Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2256
... orbitals and the levels contain 49 electrons . The scheme for the phosphine is derived from that calculated for the nitrosyls by removing the # - and -orbitals of NO from the basis , so that the levels shown correspond to a 34 orbital ...
... orbitals and the levels contain 49 electrons . The scheme for the phosphine is derived from that calculated for the nitrosyls by removing the # - and -orbitals of NO from the basis , so that the levels shown correspond to a 34 orbital ...
Page 2569
Chemical Society (Great Britain). and involving the 2p , orbital . This orbital is the one which dominates the optical spectroscopic properties of the molecule and it has its parallel in other B - N , B - O , and organoboron compounds ...
Chemical Society (Great Britain). and involving the 2p , orbital . This orbital is the one which dominates the optical spectroscopic properties of the molecule and it has its parallel in other B - N , B - O , and organoboron compounds ...
Page 2902
... orbital was approximated to near 76 kk . The ionisation energy of metal d and p orbitals are very sensitive to the effective charge and configuration of the metal atom . The energy of the 3d orbital of a metal atom will be greater than ...
... orbital was approximated to near 76 kk . The ionisation energy of metal d and p orbitals are very sensitive to the effective charge and configuration of the metal atom . The energy of the 3d orbital of a metal atom will be greater than ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow