Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2145
... Splitting Data for Tin ( iv ) Compounds By R. V. Parish * and R. H. Platt , Department of Chemistry , The University of Manchester Institute of Science and Technology , Manchester , M60 1QD Mössbauer spectroscopic data for a range of ...
... Splitting Data for Tin ( iv ) Compounds By R. V. Parish * and R. H. Platt , Department of Chemistry , The University of Manchester Institute of Science and Technology , Manchester , M60 1QD Mössbauer spectroscopic data for a range of ...
Page 2149
... splitting is found for X = alkyl , aryl , vinyl , M ( SnR3 ) , ( M = Ge , Sn , Pb ) , 1,31,33 but an increase in the electro- negativity of a carbon donor atom in X by a change from sp3 or sp2 hybridisation to sp hybridisation ( e.g. ...
... splitting is found for X = alkyl , aryl , vinyl , M ( SnR3 ) , ( M = Ge , Sn , Pb ) , 1,31,33 but an increase in the electro- negativity of a carbon donor atom in X by a change from sp3 or sp2 hybridisation to sp hybridisation ( e.g. ...
Page 2838
... splitting . 3 The Mössbauer parameters for the materials of com- position SnX4,40xH are identical to those for the corre- sponding SnX , ox2 compounds . These results are there- fore in agreement with the formulation 3,4 SnX2 0x2 ...
... splitting . 3 The Mössbauer parameters for the materials of com- position SnX4,40xH are identical to those for the corre- sponding SnX , ox2 compounds . These results are there- fore in agreement with the formulation 3,4 SnX2 0x2 ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow