Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2205
... temperatures near 150 ° . All van't Hoff plots were similar to that shown in the Figure . Each consisted of a low - temperature linear position which had a high precision in comparison with a high - temperature linear position . log A2T ...
... temperatures near 150 ° . All van't Hoff plots were similar to that shown in the Figure . Each consisted of a low - temperature linear position which had a high precision in comparison with a high - temperature linear position . log A2T ...
Page 2462
... temperature and ( B ) liquid nitrogen temperature . Spectra ( C ) and ( D ) are of a Nujol mull of 5 - NO - salen nitrosyl at room and liquid nitrogen temperatures respectively = of low - spin compound is small , and the expected de ...
... temperature and ( B ) liquid nitrogen temperature . Spectra ( C ) and ( D ) are of a Nujol mull of 5 - NO - salen nitrosyl at room and liquid nitrogen temperatures respectively = of low - spin compound is small , and the expected de ...
Page 2868
... Temperature Effects . Variation of the temperature for the diamagnetic model compound IrCl , ( PMe , Ph ) , had no effect on the proton shifts to within ± 0.02 p.p.m. We may presume then that temperature effects on the shifts in the ...
... Temperature Effects . Variation of the temperature for the diamagnetic model compound IrCl , ( PMe , Ph ) , had no effect on the proton shifts to within ± 0.02 p.p.m. We may presume then that temperature effects on the shifts in the ...
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absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow