Quarterly Journal of the Chemical Society of London, Part 1, Pages 2077-3028 |
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Page 2471
... values , are differentiated with respect to substituent , and are lower for secondary than for primary R. The effect may be re - examined by use of the constants of Table 3. In Table 4 the observed pK'1.1 values for " TABLE 4 The ...
... values , are differentiated with respect to substituent , and are lower for secondary than for primary R. The effect may be re - examined by use of the constants of Table 3. In Table 4 the observed pK'1.1 values for " TABLE 4 The ...
Page 2574
... values are so close to those of Gibson , we are able to say that the three g - values , 1 , 2 , and 3 , are directed along the x , y , and z axes respectively . In view of the axial symmetry of the 57Fe hyperfine tensor , this is taken ...
... values are so close to those of Gibson , we are able to say that the three g - values , 1 , 2 , and 3 , are directed along the x , y , and z axes respectively . In view of the axial symmetry of the 57Fe hyperfine tensor , this is taken ...
Page 2830
... values of AS ( diss ) for the chromium and tungsten carbonyls . The close- ness of the values of AH ( diss ) for these carbonyls is paralleled by the values of the C - O stretching force constants which differ by only 1 % . The ...
... values of AS ( diss ) for the chromium and tungsten carbonyls . The close- ness of the values of AH ( diss ) for these carbonyls is paralleled by the values of the C - O stretching force constants which differ by only 1 % . The ...
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Common terms and phrases
absorption acetate acetone acetonitrile acid adduct Amer analysis angles anion aqueous assigned band benzene bond lengths bromide bromine Calc calculated carbon carbonyl cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt cobalt(II complexes compounds concentration copper(II crystal dichloromethane dimethylformamide dithiolene electronic energy equation ethanol ether EXPERIMENTAL Fe3+ Figure formation frequency Gibbsite H₂O halides hydrogen atoms i.r. spectra Inorg intensity interaction iodomethane isomer k₁ kcal kinetics lattice ligand magnetic measured metal methyl mixture mmole modes molecular molecule molybdenum Mössbauer n.m.r. spectra nitrogen observed obtained octahedral orbital oxide parameters pentafluoride perchlorate phosphine Phys pK'a plane potassium powder prepared protons pyridine Raman rate constants reaction recrystallised resin room temperature salt samples shift shown similar sodium solid solution solvent species spectra spectrum stretching structure suggested symmetry Table tetrahydrofuran thiocyanate triphenylphosphine values vibrations X-ray yellow