Quarterly Journal of the Chemical Society of London, Issue 15, Pages 777-1692 |
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Page 855
... angle of rotation , would react in an oriented collision 10 times as fast as in a random collision . " Orbital steering " does not require a simplistic linear relationship between reactivity and solid angle . It merely suggests that the ...
... angle of rotation , would react in an oriented collision 10 times as fast as in a random collision . " Orbital steering " does not require a simplistic linear relationship between reactivity and solid angle . It merely suggests that the ...
Page 1038
... angle A [ P ( 2 ) -M– P ( 3 ) ] to be greater than angle B [ P ( 2 ) -M - P ( 1 ) ] or the converse , but ensures that A and B are stereochemically comparable . = Crystal structures ( diffractometer data , R values < 10 % ) have now ...
... angle A [ P ( 2 ) -M– P ( 3 ) ] to be greater than angle B [ P ( 2 ) -M - P ( 1 ) ] or the converse , but ensures that A and B are stereochemically comparable . = Crystal structures ( diffractometer data , R values < 10 % ) have now ...
Page 1512
... angle around the transition - metal atoms and the low angle at the methylene carbon atoms . The values , 7 ( C - M - CH2 - C ) , for the torsion angles about the bond M - CH2 , given in Table 2 , suggest a basic difference between the ...
... angle around the transition - metal atoms and the low angle at the methylene carbon atoms . The values , 7 ( C - M - CH2 - C ) , for the torsion angles about the bond M - CH2 , given in Table 2 , suggest a basic difference between the ...
Contents
11 August 1971 | 777 |
Electron Spin Resonance Studies of Stable Radicals Generated by Oxidation of sButyllithium with Transition | 878 |
O COPYRIGHT 1971 | 1044 |
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Common terms and phrases
absorption acetate acid Acta adduct alcohol alkaloids alkyl Amer angle anion aqueous aromatic atoms bands benzene carbon carbonyl catalyst cation CH₂ Chem chemical shifts Chemical Society Chim chloride cm-¹ co-ordination Comm complex compounds corresponding Crystal cyclic cyclopropyl D. H. R. BARTON Department of Chemistry derivatives deuterium dimethyl electron ester ether Figure formation formed gave give hydrogen hydrolysis i.r. spectrum ibid Inorg intermediate irradiation isolated isomer isomeric ketone ligand mechanism metal methanol methyl methylene mixture molecular molecule n.m.r. spectrum nitrogen nucleophilic observed obtained olefin orbitals oxidation oxygen Ph Ph phenyl phosphine photolysis Phys presence protons pyridine radical ratio react reaction rearrangement Received reduction reported resonance ring room temperature shown singlet sodium solution solvent species spectra spectroscopy stereochemistry structure studies substituted Summary synthesis Table Tetrahedron Letters thermal University X-ray yield