Quarterly Journal of the Chemical Society of London |
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Page 3278
... hydrogen chloride . The hydrido - complex ( 0-1312 g . ) was treated , in an evacuated apparatus , with a solution ( 5 c.c. ) of 1м - hydrogen chloride in 4 : 1 ethanol - water , and hydrogen ( 3.60 c.c. at 20 ° and 750 mm . ) was ...
... hydrogen chloride . The hydrido - complex ( 0-1312 g . ) was treated , in an evacuated apparatus , with a solution ( 5 c.c. ) of 1м - hydrogen chloride in 4 : 1 ethanol - water , and hydrogen ( 3.60 c.c. at 20 ° and 750 mm . ) was ...
Page 3432
... hydrogen chloride . Trisdimethylaminosilane ( 0-0306 g . , 0.190 mmole ) reacted with anhydrous hydrogen chloride ( 5.53 mmole ) at room temperature for 12 hr . The products were : trichlorosilane ( 0 · 120 mmole , 63 % ; v . p . , 67 ...
... hydrogen chloride . Trisdimethylaminosilane ( 0-0306 g . , 0.190 mmole ) reacted with anhydrous hydrogen chloride ( 5.53 mmole ) at room temperature for 12 hr . The products were : trichlorosilane ( 0 · 120 mmole , 63 % ; v . p . , 67 ...
Page 3813
... ( hydrogen ) . Thus added phosphate appears to aid the conversion of eaq . , which does not dehydrogenate ethanol , into H atoms , which do . Above pH 8 where HPO2 ions predominate , the effect disappears , and the hydrogen yield ...
... ( hydrogen ) . Thus added phosphate appears to aid the conversion of eaq . , which does not dehydrogenate ethanol , into H atoms , which do . Above pH 8 where HPO2 ions predominate , the effect disappears , and the hydrogen yield ...
Contents
NO PAGE | 2842 |
Mechanism of benzidine and semidine rearrangements Part XV A collective | 2864 |
By DAVID PETERS | 2901 |
Copyright | |
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absorption acetic acid acetone added adduct alcohol alkyl Amax Amer anhydride aqueous aromatic atom atomic orbitals band benzene bond bromine Calc carbon carbonyl cation CH₂ Chem chloroform chromatography cm.¹ complex compound concentration constant crystallised cyclohexane decomp decomposition derivatives dilute dimethyl distilled dried effect electron ester ethanol ether evaporated extracted filtered filtrate formation formed Found fraction gave give heated hydride hydrogen hydrolysis hydroxide infrared infrared spectrum iodide ionisation energies isomer kinetic light petroleum b. p. lithium lithium aluminium hydride mechanism methyl mixed m. p. mixture mole molecular molecule nitric oxide nitrogen Nujol observed obtained oxidation perchlorate phenyl potassium prepared proton pyridine reaction rearrangement reduced refluxed requires residue room temperature salt sodium sodium hydroxide solid solution solvent spectra steric steric effect structure substitution sulphate Table thionyl chloride transition ultraviolet values Vmax yield