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Page 3258
... oxidation of a - D - glucose , although corrected for mutarotation , is considered unreliable since the anomerisation and oxidation rates were obtained in different media , and , although the total bromine ( Br2 + Br ̄ ) content was ...
... oxidation of a - D - glucose , although corrected for mutarotation , is considered unreliable since the anomerisation and oxidation rates were obtained in different media , and , although the total bromine ( Br2 + Br ̄ ) content was ...
Page 3259
... oxidation of the ẞ - anomer for the two assumed cases where mutarotation was either very fast or very slow compared with oxidation . 7 + 6 18 15 x3 103k2 ( 1. mole ' min1 ) , oxidation ་ 5 ( 0 ) × 2 15 ( b ) +00 to +5 5 102k2 ( 1. mole ...
... oxidation of the ẞ - anomer for the two assumed cases where mutarotation was either very fast or very slow compared with oxidation . 7 + 6 18 15 x3 103k2 ( 1. mole ' min1 ) , oxidation ་ 5 ( 0 ) × 2 15 ( b ) +00 to +5 5 102k2 ( 1. mole ...
Page 3262
... oxidation , the net result being that the oxidation rate is proportional to the total bromine concentration . Although the rate of hydration of acetaldehyde is much greater than its rate of oxidation , the various possible ionic ...
... oxidation , the net result being that the oxidation rate is proportional to the total bromine concentration . Although the rate of hydration of acetaldehyde is much greater than its rate of oxidation , the various possible ionic ...
Contents
NO PAGE | 2842 |
Mechanism of benzidine and semidine rearrangements Part XV A collective | 2864 |
By DAVID PETERS | 2901 |
Copyright | |
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absorption acetic acid acetone added adduct alcohol alkyl Amax Amer anhydride aqueous aromatic atom atomic orbitals band benzene bond bromine Calc carbon carbonyl cation CH₂ Chem chloroform chromatography cm.¹ complex compound concentration constant crystallised cyclohexane decomp decomposition derivatives dilute dimethyl distilled dried effect electron ester ethanol ether evaporated extracted filtered filtrate formation formed Found fraction gave give heated hydride hydrogen hydrolysis hydroxide infrared infrared spectrum iodide ionisation energies isomer kinetic light petroleum b. p. lithium lithium aluminium hydride mechanism methyl mixed m. p. mixture mole molecular molecule nitric oxide nitrogen Nujol observed obtained oxidation perchlorate phenyl potassium prepared proton pyridine reaction rearrangement reduced refluxed requires residue room temperature salt sodium sodium hydroxide solid solution solvent spectra steric steric effect structure substitution sulphate Table thionyl chloride transition ultraviolet values Vmax yield