Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 236
... Benzene- Solute Complexes By K. M. Baker * and R. G. Wilson , University Chemical Laboratory , Cambridge The stoichiometry of association between benzene and several polar solutes has been determined from the solvent shifts at various ...
... Benzene- Solute Complexes By K. M. Baker * and R. G. Wilson , University Chemical Laboratory , Cambridge The stoichiometry of association between benzene and several polar solutes has been determined from the solvent shifts at various ...
Page 237
... benzene respectively , & is the difference in shift from an ' inert ' solvent for a benzene solution , and SAв the shift difference in the pure complex between solute and benzene , then K = x . 8 / 8AB x ( 18 / 8AB ) ( y xn . 8 / 8AB ) ...
... benzene respectively , & is the difference in shift from an ' inert ' solvent for a benzene solution , and SAв the shift difference in the pure complex between solute and benzene , then K = x . 8 / 8AB x ( 18 / 8AB ) ( y xn . 8 / 8AB ) ...
Page 238
... benzene only , plots of log ( 8 / [ SAB — 8 ] ) versus log ( concentration of benzene ) log [ concentration ( mole 1. - 1 ) toluene ] 0.8 -0.2 log [ 5 / ( $ AB - 5 ) ] -0.4 FIGURE 1 Chloroform in deuteriotoluene gave straight lines ...
... benzene only , plots of log ( 8 / [ SAB — 8 ] ) versus log ( concentration of benzene ) log [ concentration ( mole 1. - 1 ) toluene ] 0.8 -0.2 log [ 5 / ( $ AB - 5 ) ] -0.4 FIGURE 1 Chloroform in deuteriotoluene gave straight lines ...
Contents
Physical organic chemistry | 1 |
Topochemistry Part XXX Crystal and molecular structures of chalcone | 11 |
Conformational studies Part I Crystal and molecular structures of cis12dipchlorobenzoyl and cis | 17 |
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acetic acid activation added addition alcohol Amer angle appears aqueous assumed ation atoms base benzene bond bromination calculated carbon carbon tetrachloride Chem chemical Chemistry chloride compared complex compounds concentration conformation containing corresponding coupling crystal dependence derivatives determined difference DISCUSSION effect elimination energy equation error estimated ethanol ether exchange expected experimental experiments Figure formation fraction give given hydrogen increase indicators interaction intermediate involving isomer isotope kinetic measured mechanism method methyl mixture mole molecular molecule observed obtained occurs oxide oxygen parameters Phys plot position possible prepared present proton radical range rate constants ratio reaction reasonable relative reported requires respectively ring shifts shown shows similar sodium solution solvent spectra spectrum structure substituents suggested sulphuric Table temperature transition University values wave yield