Quarterly Journal of the Chemical Society of London, Volume 1 |
From inside the book
Results 1-3 of 85
Page 39
... intermediate respectively . The value of 4 is that expected for reduction of the inter- mediate to an amino - ketone . 100 80 60 FIGURE 9 From left to right , polarograms of 4.4 × 10 - M p - bromo - w - diazoacetophenone in 0.1M ...
... intermediate respectively . The value of 4 is that expected for reduction of the inter- mediate to an amino - ketone . 100 80 60 FIGURE 9 From left to right , polarograms of 4.4 × 10 - M p - bromo - w - diazoacetophenone in 0.1M ...
Page 342
... intermediate . 2,4,6 - Trimethyl- 91 · 8 % H2SO , 25.0 acetophenone 87.0 % H2SO 25.0 oxime 85-8 % H2SO 25.0 85.8 % H2SO4 33.8 85.8 % H2SO4 48.0 84.7 % H2SO , 81.9 % H2SO4 25-0 77.4 % H2SO 25.0 71.8 % HCIO 25.0 71.8 % HCIO 30-2 0.054 ...
... intermediate . 2,4,6 - Trimethyl- 91 · 8 % H2SO , 25.0 acetophenone 87.0 % H2SO 25.0 oxime 85-8 % H2SO 25.0 85.8 % H2SO4 33.8 85.8 % H2SO4 48.0 84.7 % H2SO , 81.9 % H2SO4 25-0 77.4 % H2SO 25.0 71.8 % HCIO 25.0 71.8 % HCIO 30-2 0.054 ...
Page 343
... intermediate was obtained in the studies of the rearrangements of acetophen- one oxime and its meta- and para - substituted derivatives , but it seems likely that in these cases a similar intermediate is formed in a rate - determining ...
... intermediate was obtained in the studies of the rearrangements of acetophen- one oxime and its meta- and para - substituted derivatives , but it seems likely that in these cases a similar intermediate is formed in a rate - determining ...
Contents
Physical organic chemistry | 1 |
Topochemistry Part XXX Crystal and molecular structures of chalcone | 11 |
Conformational studies Part I Crystal and molecular structures of cis12dipchlorobenzoyl and cis | 17 |
25 other sections not shown
Other editions - View all
Common terms and phrases
acetic acid activation added addition alcohol Amer angle appears aqueous assumed ation atoms base benzene bond bromination calculated carbon carbon tetrachloride Chem chemical Chemistry chloride compared complex compounds concentration conformation containing corresponding coupling crystal dependence derivatives determined difference DISCUSSION effect elimination energy equation error estimated ethanol ether exchange expected experimental experiments Figure formation fraction give given hydrogen increase indicators interaction intermediate involving isomer isotope kinetic measured mechanism method methyl mixture mole molecular molecule observed obtained occurs oxide oxygen parameters Phys plot position possible prepared present proton radical range rate constants ratio reaction reasonable relative reported requires respectively ring shifts shown shows similar sodium solution solvent spectra spectrum structure substituents suggested sulphuric Table temperature transition University values wave yield