Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 163
... involving ketens and acids . The corresponding gas - phase reactions which are thermodynamically feasible under reaction conditions are ( 10 ) - ( 13 ) . None of these intermediates CH2 : C : CH2 + H2O — CH3.CO · CH2 ( 10 ) CHg • COCH ...
... involving ketens and acids . The corresponding gas - phase reactions which are thermodynamically feasible under reaction conditions are ( 10 ) - ( 13 ) . None of these intermediates CH2 : C : CH2 + H2O — CH3.CO · CH2 ( 10 ) CHg • COCH ...
Page 212
... involving stable organic cations.12 From the detailed kinetic data shown in Table 1 ( average values of k2 were reproducible to within 10 % ) , it may be deduced that the hydride specific rates of reactions involving charge dispersal in ...
... involving stable organic cations.12 From the detailed kinetic data shown in Table 1 ( average values of k2 were reproducible to within 10 % ) , it may be deduced that the hydride specific rates of reactions involving charge dispersal in ...
Page 1014
... involving a cyclic transition state like ( III ) which facilitates leaving - group departure . This conclusion is , of course , precisely that expected in the light of other work . The studies of Anderson et al . with diaminopropanes ...
... involving a cyclic transition state like ( III ) which facilitates leaving - group departure . This conclusion is , of course , precisely that expected in the light of other work . The studies of Anderson et al . with diaminopropanes ...
Contents
Physical organic chemistry | 1 |
Topochemistry Part XXX Crystal and molecular structures of chalcone | 11 |
Conformational studies Part I Crystal and molecular structures of cis12dipchlorobenzoyl and cis | 17 |
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4-nitroaniline A. R. Katritzky acetic acid activation energy alcohol Amer amine anion aqueous aromatic aryl-methyl ation axial benzene bond bond dissociation energies bromination calculated carbanion carbon acids catalyst Chem chemical shifts Chemistry chloride compounds concentration conformation corresponding coupling constants crystal cyclohexane derivatives deviations dilute dimethyl sulphoxide dipole electron equation ether ethylene experimental Figure fluorene formation fraction H₂O hydrocarbons hydroxide increase indicators interactions intermediate ionisation isomer isomerization isotope effect k₁ k₂ kcal kcal./mole kinetic Mc./sec measured mechanism methanol methyl mixture mole mole-¹ molecular molecules n.m.r. spectra nitrogen nucleophilic observed obtained oxide oxygen parameters phenyl Phys piperidine proton pyridines R. P. Bell radical rate constants ratio reaction relative ring selenophen shown shows signal sodium solution solvent spectrum structure substituted t-butyl Table temperature Tetrahedron thiophen transition tri-o-thymotide triethylamine triphenylmethane wave