Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 458
... plot 8RT / 3000 ( 3 ) od = does not extrapolate to zero at zero fluidity and the intercept should presumably give a measure of the quenching constant due to the association process . The fluidity dependence shows that the quenching is ...
... plot 8RT / 3000 ( 3 ) od = does not extrapolate to zero at zero fluidity and the intercept should presumably give a measure of the quenching constant due to the association process . The fluidity dependence shows that the quenching is ...
Page 473
... plot with four out of six points , P 16 ) . = = Taft obtained a straight line by plotting the pK of several carbon acids against 260R- + 4201.39 Using the same o - combination against log ką , we obtained a straight line for the CO2Me ...
... plot with four out of six points , P 16 ) . = = Taft obtained a straight line by plotting the pK of several carbon acids against 260R- + 4201.39 Using the same o - combination against log ką , we obtained a straight line for the CO2Me ...
Page 474
... plot of Friedman's log k's for the reaction of glycine with electrophilic olefins against pK is linear log k ( A ) log k ( B ) log k -2 2 5 10 44 ბო ო 22 27 25 67 23 21 19 рка FIGURE 2 Plot of log k , for the addition of morpholine ...
... plot of Friedman's log k's for the reaction of glycine with electrophilic olefins against pK is linear log k ( A ) log k ( B ) log k -2 2 5 10 44 ბო ო 22 27 25 67 23 21 19 рка FIGURE 2 Plot of log k , for the addition of morpholine ...
Contents
Physical organic chemistry | 1 |
Topochemistry Part XXX Crystal and molecular structures of chalcone | 11 |
Conformational studies Part I Crystal and molecular structures of cis12dipchlorobenzoyl and cis | 17 |
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A. R. Katritzky alcohol alkyl Amer anion aqueous aromatic ation axial benzene bond bromination calculated carbanion carbon acids carbon atom carbon tetrachloride carbonyl catalyst Chem chemical shifts Chemistry chloride complex compounds concentration conformation correlation coupling constants crystal cyclohexane derivatives difference dilute dimethyl sulphoxide dioxan electron elimination energy equation equatorial equilibrium ester ethanol ether experimental Figure fluorene formation fraction H₂O H₂SO hydrogen hydrolysis hydroxide indicators interaction intermediate ionisation isomer isomerization isotope effect k₁ k₂ kcal kcal./mole kinetic measured mechanism methyl mixture mole mole-¹ molecular molecule n.m.r. spectra nitration nitrogen nucleophilic observed obtained oxide oxime oxygen parameters phenyl Phys piperidine plot proton pyridines R. P. Bell radical rate constants ratio reaction reactivity ring shown shows sodium solution solvent spectrum structure substituents sulphuric acid t-butyl Table temperature Tetrahedron thiophen transition values