Quarterly Journal of the Chemical Society of London, Part 3 |
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Page 2355
... amines with increasing size is probably due to the smaller solvation of the cations of the larger amines , since , of each pair of amines with the same or nearly the same charge density , it is the conjugate acid of the larger amine ...
... amines with increasing size is probably due to the smaller solvation of the cations of the larger amines , since , of each pair of amines with the same or nearly the same charge density , it is the conjugate acid of the larger amine ...
Page 2356
Chemical Society (Great Britain). corresponding to the amine , 11 the difference in -electron energy between a monoaza- heteroaromatic amine and its cation , AE ,, is given by ΔΕΠ AE = 9N ( C1AαNH - - . ( 3 ) where qN and qo are the ...
Chemical Society (Great Britain). corresponding to the amine , 11 the difference in -electron energy between a monoaza- heteroaromatic amine and its cation , AE ,, is given by ΔΕΠ AE = 9N ( C1AαNH - - . ( 3 ) where qN and qo are the ...
Page 2471
... amine . ( b ) Solutions of the amine in AnalaR " carbon tetrachloride and hexane , in presence of air , slowly deposited a red - violet precipitate : this gave a red solution in chloroform , which turned yellow- orange with alumina ...
... amine . ( b ) Solutions of the amine in AnalaR " carbon tetrachloride and hexane , in presence of air , slowly deposited a red - violet precipitate : this gave a red solution in chloroform , which turned yellow- orange with alumina ...
Contents
ABEL E W Bennett M A and Wilkinson G | 2323 |
Bourne E J Hartigan J and Weigel H | 2332 |
Clark E R | 2344 |
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1,3,5-trinitrobenzene absorption acetic acid acetic anhydride acetone added alcohol alkaline alkyl Amer amine ammonia anhydride atom benzene boiling bond bromide Calc carbon Chem chloride chloroform chromatography complex compound concentration constant cooled crystallised crystals curve decomp derivatives diethylamine dilute dimer dioxan dioxide dissolved distilled dried eluted ester ethanol evaporated filtered filtrate formation formed Found fraction gave give glycollic acid glyoxylic acid heated hydride hydrochloric acid hydrolysis hydroxide infrared infrared spectrum iodide isolated isomer K₁ light petroleum b. p. lithium lithium aluminium hydride m. p. and mixed methyl methyl iodide mixed m. p. mixture mole molecular molecule nitrogen obtained oxidation oxygen perchlorate picrate polymer potassium precipitate prepared prisms pyridine reaction reduced refluxed requires residue room temperature salt sodium hydroxide solid solvent spectra stirred structure sulphuric acid Table titration ultraviolet values washed yield