Quarterly Journal of the Chemical Society of London, Part 3 |
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Page 2484
... hydride , H2Fe ( CO ) , by Hieber and Leutert , 1 other transition - metal carbonyl hydrides have been claimed , but of these only the cobalt 2 and manganese compounds have been well characterized . Until recently , the iron and cobalt ...
... hydride , H2Fe ( CO ) , by Hieber and Leutert , 1 other transition - metal carbonyl hydrides have been claimed , but of these only the cobalt 2 and manganese compounds have been well characterized . Until recently , the iron and cobalt ...
Page 2595
... hydride and various analogues also clearly depends on the effective size of the reducing anion.5 Moreover , these hydride reductions are considered to be bimolecular replacements so that steric factors should operate . To test further ...
... hydride and various analogues also clearly depends on the effective size of the reducing anion.5 Moreover , these hydride reductions are considered to be bimolecular replacements so that steric factors should operate . To test further ...
Page 2773
... hydride ion and a proton , the key step being removal of the hydride ion . Necessary structural features in the substrate are discussed . Application of the reagent in a new synthesis of perinaphthenylium salts is described ...
... hydride ion and a proton , the key step being removal of the hydride ion . Necessary structural features in the substrate are discussed . Application of the reagent in a new synthesis of perinaphthenylium salts is described ...
Contents
ABEL E W Bennett M A and Wilkinson G | 2323 |
Bourne E J Hartigan J and Weigel H | 2332 |
Clark E R | 2344 |
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Common terms and phrases
1,3,5-trinitrobenzene absorption acetic acid acetic anhydride acetone added alcohol alkaline alkyl Amer amine ammonia anhydride atom benzene boiling bond bromide Calc carbon Chem chloride chloroform chromatography complex compound concentration constant cooled crystallised crystals curve decomp derivatives diethylamine dilute dimer dioxan dioxide dissolved distilled dried eluted ester ethanol evaporated filtered filtrate formation formed Found fraction gave give glycollic acid glyoxylic acid heated hydride hydrochloric acid hydrolysis hydroxide infrared infrared spectrum iodide isolated isomer K₁ light petroleum b. p. lithium lithium aluminium hydride m. p. and mixed methyl methyl iodide mixed m. p. mixture mole molecular molecule nitrogen obtained oxidation oxygen perchlorate picrate polymer potassium precipitate prepared prisms pyridine reaction reduced refluxed requires residue room temperature salt sodium hydroxide solid solvent spectra stirred structure sulphuric acid Table titration ultraviolet values washed yield