Quarterly Journal of the Chemical Society of London, Part 3 |
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Page 2415
... increase . Since ( S / V ) is a measure of the rate at which the entropy increases when the molecules of the liquid are separated isothermally , it should be greater the more ordered the liquid and the more disorder it has to gain on ...
... increase . Since ( S / V ) is a measure of the rate at which the entropy increases when the molecules of the liquid are separated isothermally , it should be greater the more ordered the liquid and the more disorder it has to gain on ...
Page 2419
... increased number of configurations available to the molecules , but that with the longer molecules the greater tendency towards a parallel alignment leads to an increase in internal order which is reflected in increasing values for the ...
... increased number of configurations available to the molecules , but that with the longer molecules the greater tendency towards a parallel alignment leads to an increase in internal order which is reflected in increasing values for the ...
Page 2536
... increase in that order , as is shown by the following mean rate - constants ( 1. mole - 1 sec . - 1 ) of reaction in ethanol at the temperatures noted : HgBr2 , 0.39 at 25 ° ; Hg ( OAc ) 2 , 5 · 3 at 0 ° ; Hg ( NO3 ) 2 , 7 · 6 at —46 ...
... increase in that order , as is shown by the following mean rate - constants ( 1. mole - 1 sec . - 1 ) of reaction in ethanol at the temperatures noted : HgBr2 , 0.39 at 25 ° ; Hg ( OAc ) 2 , 5 · 3 at 0 ° ; Hg ( NO3 ) 2 , 7 · 6 at —46 ...
Contents
ABEL E W Bennett M A and Wilkinson G | 2323 |
Bourne E J Hartigan J and Weigel H | 2332 |
Clark E R | 2344 |
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1,3,5-trinitrobenzene absorption acetic acid acetic anhydride acetone added alcohol alkaline alkyl Amer amine ammonia anhydride atom benzene boiling bond bromide Calc carbon Chem chloride chloroform chromatography complex compound concentration constant cooled crystallised crystals curve decomp derivatives diethylamine dilute dimer dioxan dioxide dissolved distilled dried eluted ester ethanol evaporated filtered filtrate formation formed Found fraction gave give glycollic acid glyoxylic acid heated hydride hydrochloric acid hydrolysis hydroxide infrared infrared spectrum iodide isolated isomer K₁ light petroleum b. p. lithium lithium aluminium hydride m. p. and mixed methyl methyl iodide mixed m. p. mixture mole molecular molecule nitrogen obtained oxidation oxygen perchlorate picrate polymer potassium precipitate prepared prisms pyridine reaction reduced refluxed requires residue room temperature salt sodium hydroxide solid solvent spectra stirred structure sulphuric acid Table titration ultraviolet values washed yield