Journal of the Chemical SocietyThe Society., 1947 |
From inside the book
Results 1-3 of 11
Page 1011
... Pu ( IV ) may be reduced to Pu ( III ) by sulphur dioxide , hydroxylamine hydrochloride , the uranous ion , hydrazine hydrochloride , the iodide ion , electrolytically at a platinum cathode , or by shaking with mercury in chloride ...
... Pu ( IV ) may be reduced to Pu ( III ) by sulphur dioxide , hydroxylamine hydrochloride , the uranous ion , hydrazine hydrochloride , the iodide ion , electrolytically at a platinum cathode , or by shaking with mercury in chloride ...
Page 1020
... Pu ( IV ) on lanthanum fluoride . Total wt . of La used , mg./ml . of Pu soln . % Pu remaining in solution ... 0.35 1.49 0.093 1.94 0.034 6.11 0.017 10.4 ( I ) A sample of sulphate crystals ( see p . 1012 ) was separated from the ...
... Pu ( IV ) on lanthanum fluoride . Total wt . of La used , mg./ml . of Pu soln . % Pu remaining in solution ... 0.35 1.49 0.093 1.94 0.034 6.11 0.017 10.4 ( I ) A sample of sulphate crystals ( see p . 1012 ) was separated from the ...
Page 1021
... Pu carried down on Th , La and Zr salts Green - yellow ppt . Ion . Reagent . pH range . Pu ( VI ) 8 - Hydroxyquinoline 4-8 Reaction . Orange - brown ppt . extractable in amyl acetate Pu ( IV ) ... Pu ( IV ) Anthranilic acid 3 Pu ( IV ) ...
... Pu carried down on Th , La and Zr salts Green - yellow ppt . Ion . Reagent . pH range . Pu ( VI ) 8 - Hydroxyquinoline 4-8 Reaction . Orange - brown ppt . extractable in amyl acetate Pu ( IV ) ... Pu ( IV ) Anthranilic acid 3 Pu ( IV ) ...
Other editions - View all
Common terms and phrases
absorption acetic acid acetone activity added alkali Amer amidine ammonia anhydride atoms band benzene boiling bromine Calc carbon carbon tetrachloride catalyst CH₂ Chem chemical chemistry chloroform compound concentrated condensation cooled crystallised crystals cyanide D.Sc decomp derivatives dilute dissolved distilled dried equiv ester evaporated experimental extracted with ether filtered filtrate formation formed Found fraction gave give H₂ heated hydrochloric acid hydrochloride hydrogen chloride hydrolysis iodide iodine isolated isotherm ketone l-arabinose lactone light petroleum b. p. liquid m. p. and mixed methanol method methyl alcohol mixed m. p. mixture molecular molecule nitration obtained oxide oxidised phenyl phosphoryl chloride picrate polymerisation potassium precipitated prepared Pu(IV pyridine reaction reduced pressure refluxed removed requires residue salt separated sodium hydroxide solid soluble solvent stirred structure sulphate sulphuric acid syrup vacuum vinyl acetate washed yellow yield