Journal of the Chemical SocietyThe Society., 1947 |
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Page 1119
... Iodine in Various Solutions . Part II . Solutions of Iodine in Organic Solvents . By L. L. BIRCUMSHAW and M. H. Everdell . = The kinetics of the reaction between copper and iodine when dissolved in carbon tetrachloride , chloroform ...
... Iodine in Various Solutions . Part II . Solutions of Iodine in Organic Solvents . By L. L. BIRCUMSHAW and M. H. Everdell . = The kinetics of the reaction between copper and iodine when dissolved in carbon tetrachloride , chloroform ...
Page 1126
... iodine in carbon tetrachloride at 25 ° . Time , mins . Χο x ( no previous film ) 10 20 30 60 120 180 0.83 3.75 1.45 4.88 1-85 3.04 5.57 7.48 5.88 7.96 11.46 14.135 ( 2 ) Copper covered by cuprous iodide film formed in carbon ...
... iodine in carbon tetrachloride at 25 ° . Time , mins . Χο x ( no previous film ) 10 20 30 60 120 180 0.83 3.75 1.45 4.88 1-85 3.04 5.57 7.48 5.88 7.96 11.46 14.135 ( 2 ) Copper covered by cuprous iodide film formed in carbon ...
Page 1170
... iodine caused a very considerable acceleration of the rate , and the measurements , now found to be reproducible ... iodine is shown in Fig . 4 , the average t1 / t , ratios being : M / 1000 - м / 500 , 19 ; м / 500 - м / 250 , n = 1.95 ...
... iodine caused a very considerable acceleration of the rate , and the measurements , now found to be reproducible ... iodine is shown in Fig . 4 , the average t1 / t , ratios being : M / 1000 - м / 500 , 19 ; м / 500 - м / 250 , n = 1.95 ...
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Common terms and phrases
absorption acetic acid acetone activity added addition alkali Amer amidine ammonia anhydride atoms band benzene boiling bromine Calc carbon carbon tetrachloride catalyst CH₂ Chem chemical chemistry chloroform compound concentrated condensation cooled crystallised crystals cyanide D.Sc decomp derivatives dilute dissolved distilled dried equiv ester evaporated experimental extracted with ether filtered filtrate formation formed Found fraction gave give H₂ heated hydrochloric acid hydrochloride hydrogen chloride hydrolysis iodide iodine isolated isotherm ketone l-arabinose lactone light petroleum b. p. liquid m. p. and mixed methanol method methyl alcohol mixed m. p. mixture molecular molecule nitration obtained oxide oxidised phenyl phosphoryl chloride picrate polymerisation potassium precipitated prepared pyridine reaction reduced pressure refluxed removed requires residue salt separated sodium hydroxide solid soluble solvent stirred structure sulphate sulphuric acid syrup vacuum vinyl acetate washed yellow yield