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Page 1098
... nitrate , dissociation constants in a number of different solvents are available ; values of K , a , and △ ŋ are given in Table II . Although there is a general tendency for K to TABLE II . The dissociation constant and a parameter of ...
... nitrate , dissociation constants in a number of different solvents are available ; values of K , a , and △ ŋ are given in Table II . Although there is a general tendency for K to TABLE II . The dissociation constant and a parameter of ...
Page 1691
... nitrate ( IV ) , m . p . 143 ° ( private communication from Professor Marvin Carmack ) . According as Knudsen's nitrate has structure ( III ) or ( II ) of Part I , it should give either ( IV ) or 3 : 7 - dinitro - 1 : 5 - dimethyl - 1 ...
... nitrate ( IV ) , m . p . 143 ° ( private communication from Professor Marvin Carmack ) . According as Knudsen's nitrate has structure ( III ) or ( II ) of Part I , it should give either ( IV ) or 3 : 7 - dinitro - 1 : 5 - dimethyl - 1 ...
Page 1692
... nitrate . = C , % . H , % . N , % . % - % . Anion Xe , % Found SFrom Knudsen's nitrate 24-7 4.6 33.1 4.0 24.1 21.51 Calc . From hexamine methonitrate ( For C16H130 , N , ( IV ) 24.5 4.5 33.6 4.2 23.6 21.1 nitrate 24.4 4.4 33.2 5.1 23.8 ...
... nitrate . = C , % . H , % . N , % . % - % . Anion Xe , % Found SFrom Knudsen's nitrate 24-7 4.6 33.1 4.0 24.1 21.51 Calc . From hexamine methonitrate ( For C16H130 , N , ( IV ) 24.5 4.5 33.6 4.2 23.6 21.1 nitrate 24.4 4.4 33.2 5.1 23.8 ...
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absorption acetic anhydride acetone acetyl added alcohol alkaline alunite Amer amine ammonia anhydrous anilide aqueous sodium atom benzene boiling bromine trifluoride Calc carbonate CH₂ Chem chloroform colour colourless needles compound condensation containing cooled crystallised crystals cyanide cyclisation D.Sc decomp derivatives dilute dissolved distilled dried equiv ester ethanol ethyl acetate evaporated EXPERIMENTAL extracted with ether filtered filtrate fluoride formation formed Found fraction gave give heated under reflux hydrochloric acid hydrogen chloride hydrolysis iodide iodine ions isolated kcals ketone light petroleum b. p. liquid melting method methyl minutes mixed m. p. molecule nitrate nitrile nitrogen obtained oxalate oxide oxime oxygen pickeringite picrate piperidine potassium potassium hydroxide precipitate prepared prisms pyridine reductive dissolution removed requires residue room temperature salt semicarbazone separated sodium hydroxide solid soluble solvent specimen sulphate sulphuric acid values washed xylose yellow needles yield