Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1148
... concentration . The rate laws observed are v = k'3 [ H + ] [ HNO2 ] [ NO ] and v = k'1 [ H + ] 2 [ HNO2 ] [ NO , ̄ ] [ SCN- ] at high and low concentrations of thiocyanate respectively . The mech- anism postulated involves the formation ...
... concentration . The rate laws observed are v = k'3 [ H + ] [ HNO2 ] [ NO ] and v = k'1 [ H + ] 2 [ HNO2 ] [ NO , ̄ ] [ SCN- ] at high and low concentrations of thiocyanate respectively . The mech- anism postulated involves the formation ...
Page 1149
... concentration is shown in the Figure , and it can be seen that there are two distinct parts to the curve . At low concentrations of thiocyanate k1 increases approximately linearly with [ CNS ] , whereas at higher concentrations it is ...
... concentration is shown in the Figure , and it can be seen that there are two distinct parts to the curve . At low concentrations of thiocyanate k1 increases approximately linearly with [ CNS ] , whereas at higher concentrations it is ...
Page 1950
... concentrations in Figure 5 are considered . Influence of the Extractant Concentration . - The influence of the extractant concentration on the extraction of tracer iron from thiocyanate solutions is shown in Figure 6 for ...
... concentrations in Figure 5 are considered . Influence of the Extractant Concentration . - The influence of the extractant concentration on the extraction of tracer iron from thiocyanate solutions is shown in Figure 6 for ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow