Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1148
... increase in nitrite concentration . The rate laws observed are v = k'3 [ H + ] [ HNO2 ] [ NO ] and v = k'1 [ H + ] 2 [ HNO2 ] [ NO , ̄ ] [ SCN- ] at high and low concentrations of thiocyanate respectively . The mech- anism postulated ...
... increase in nitrite concentration . The rate laws observed are v = k'3 [ H + ] [ HNO2 ] [ NO ] and v = k'1 [ H + ] 2 [ HNO2 ] [ NO , ̄ ] [ SCN- ] at high and low concentrations of thiocyanate respectively . The mech- anism postulated ...
Page 1529
... increase in I , between scandium and zinc has been attributed to the increase in nuclear charge , AG ° O 298 kcal./mole Sc Ti Cr Mn Fe Co Ni Cu Zn FIGURE 1 Values of AG ° 299 and I , [ equation ( 1 ) ] for the first transition series ...
... increase in I , between scandium and zinc has been attributed to the increase in nuclear charge , AG ° O 298 kcal./mole Sc Ti Cr Mn Fe Co Ni Cu Zn FIGURE 1 Values of AG ° 299 and I , [ equation ( 1 ) ] for the first transition series ...
Page 1617
... increase in log101 between 590 ° and 600 ° comes to ca. 0-16 by interpolation into Table 2 ; this corresponds to an increase of approximately five - fold in J , which is far too small to account for the observed change in luminosity ...
... increase in log101 between 590 ° and 600 ° comes to ca. 0-16 by interpolation into Table 2 ; this corresponds to an increase of approximately five - fold in J , which is far too small to account for the observed change in luminosity ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow