Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1241
... kcal . mole1 based on subsequent data for reaction ( 3 ) : CD3 + ( CD3 ) 2CO = CD ̧ + CD2 · CO · ĊD1⁄2 ( 3 ) At the same time 4 they suggested amended values of E1 = 11 · 0 and 11-4 kcal . mole - 1 from the CH , experi- ments , 2,3 on ...
... kcal . mole1 based on subsequent data for reaction ( 3 ) : CD3 + ( CD3 ) 2CO = CD ̧ + CD2 · CO · ĊD1⁄2 ( 3 ) At the same time 4 they suggested amended values of E1 = 11 · 0 and 11-4 kcal . mole - 1 from the CH , experi- ments , 2,3 on ...
Page 1371
... ( kcal . mole1 ) A142 -0.160.18 0.96 0.23 1.290-09 2.5 ± 0.3 3.390.2 42.63.3 give the Arrhenius parameters with respect to methyl chloride from the relative Arrhenius parameters obtained earlier . These values are shown in Table 3 ...
... ( kcal . mole1 ) A142 -0.160.18 0.96 0.23 1.290-09 2.5 ± 0.3 3.390.2 42.63.3 give the Arrhenius parameters with respect to methyl chloride from the relative Arrhenius parameters obtained earlier . These values are shown in Table 3 ...
Page 1856
... kcal./mole . These data correspond to a maximum possible value of 1.41 kcal./mole for AG at 30 ° which in turn means that at this temperature 9 % of the molecules are in conformer ( V ) and 45.5 % each in ( IV ) and ( VI ) . This ...
... kcal./mole . These data correspond to a maximum possible value of 1.41 kcal./mole for AG at 30 ° which in turn means that at this temperature 9 % of the molecules are in conformer ( V ) and 45.5 % each in ( IV ) and ( VI ) . This ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow