Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1431
... polarised along the short axis of the free ligand , and has A symmetry for excitations which are long - axis or perpendicularly polarised . The electronic transitions of a trischelated complex ion deriving from ligand excitations which ...
... polarised along the short axis of the free ligand , and has A symmetry for excitations which are long - axis or perpendicularly polarised . The electronic transitions of a trischelated complex ion deriving from ligand excitations which ...
Page 1438
... polarised , and they couple in the trischelated complex ( Figure 7b ) to give a resultant doubly degenerate transition , polarised perpendicular to the three - fold rotational axis of the complex , containing the whole dipole strength ...
... polarised , and they couple in the trischelated complex ( Figure 7b ) to give a resultant doubly degenerate transition , polarised perpendicular to the three - fold rotational axis of the complex , containing the whole dipole strength ...
Page 1440
... polarised charge - transfer transitions of the monochelated complex , which have a vanishing intrinsic moment ( equations 40 and 41 ) , mix with the ligand excitations of the same polarisation and acquire some 5 % of the dipole strength ...
... polarised charge - transfer transitions of the monochelated complex , which have a vanishing intrinsic moment ( equations 40 and 41 ) , mix with the ligand excitations of the same polarisation and acquire some 5 % of the dipole strength ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow