Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1146
... sulphur not accounted for was ca. 2 : 1 ( Table 1 , column R ) , which suggested the presence of sulphur dicyanide . This was confirmed by iodimetric analysis . 21+ S ( CN ) 2 I2 + SCN + CN- The liberated iodine accounted quantitatively ...
... sulphur not accounted for was ca. 2 : 1 ( Table 1 , column R ) , which suggested the presence of sulphur dicyanide . This was confirmed by iodimetric analysis . 21+ S ( CN ) 2 I2 + SCN + CN- The liberated iodine accounted quantitatively ...
Page 1148
... sulphur dicyanide is formed in the early stages of reaction , and that the products pro- duced first are sulphuric acid and hydrogen cyanide . The stoicheiometries increase or decrease as reaction proceeds ( data not shown ) in the ...
... sulphur dicyanide is formed in the early stages of reaction , and that the products pro- duced first are sulphuric acid and hydrogen cyanide . The stoicheiometries increase or decrease as reaction proceeds ( data not shown ) in the ...
Page 1480
... sulphur dioxide and sulphito - compounds were in- vestigated . With sulphur dioxide in solution the reaction was influenced by acidity . The addition of saturated aqueous sulphur dioxide to a solution of the hexammine in dilute ...
... sulphur dioxide and sulphito - compounds were in- vestigated . With sulphur dioxide in solution the reaction was influenced by acidity . The addition of saturated aqueous sulphur dioxide to a solution of the hexammine in dilute ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow