Quarterly Journal of the Chemical Society of London, Part 1, Pages 1033-2076 |
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Page 1049
... thiocyanate with 2,2 ' - bipyridyl and 1,10 - phenanthroline.1,2 These thiocyanate complexes These thiocyanate complexes were obtained using an ethereal extract from an aqueous solution containing scandium chloride and a large excess of ...
... thiocyanate with 2,2 ' - bipyridyl and 1,10 - phenanthroline.1,2 These thiocyanate complexes These thiocyanate complexes were obtained using an ethereal extract from an aqueous solution containing scandium chloride and a large excess of ...
Page 1149
... thiocyanate concentration is shown in the Figure , and it can be seen that there are two distinct parts to the curve . At low concentrations of thiocyanate k1 increases approximately linearly with [ CNS ] , whereas at higher ...
... thiocyanate concentration is shown in the Figure , and it can be seen that there are two distinct parts to the curve . At low concentrations of thiocyanate k1 increases approximately linearly with [ CNS ] , whereas at higher ...
Page 1150
... thiocyanate concentrations , and thus removes a minor anomaly in the kinetics . The corresponding corrected value of k is called k ' . For the thiocyanate- dependent region this correction is small and [ SCN- ] · [ CNS ] . = The fact ...
... thiocyanate concentrations , and thus removes a minor anomaly in the kinetics . The corresponding corrected value of k is called k ' . For the thiocyanate- dependent region this correction is small and [ SCN- ] · [ CNS ] . = The fact ...
Contents
Dolcetti G See Peloso A 1506 | 1031 |
Structures of cyclic amides Part III Thio and selenolactams | 1033 |
Equilibria in solutions which contain a metal ion and an aminoacid | 1039 |
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¹H n.m.r. spectrum absorption acetaldehyde acetone acid adduct Amer anion aqueous atoms bands benzene bond bromine trifluoride calculated carbon catalyst cation Chem chemical Chemistry chloride cm.¹ co-ordination cobalt(II coefficients complexes compounds concentration configuration corresponding coupling constant crystals cyanide dehy gel dichloromethane dilute doublet electronic energy equation ethanol ether experimental Figure five-co-ordinate fluorine formation frequencies halide heat hydrogen hydrogen cyanide hydrolysis i.r. spectra Inorg iodide iodobenzene isomers k₁ kcal lactams ligand magnetic Mc./sec measured metal methyl mixture mmoles mole-¹ molecular molecule n.m.r. spectra nickel nickel(II nitric oxide nitrogen observed obtained octahedral orbital oxygen parameters phosphine phosphorus Phys plexes PMe,Ph potassium prepared present proton Raman reaction resonance room temperature sample scandium(III showed shown similar sodium solid solution solvent species structure sulphur Table thallium thio thiocyanate thiocyanogen thiolactams titration trans trimethylsilyl tris(trimethylsilyl values yellow