Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 149
... Alkaline Hydrolysis of Methyl 2 - Aroyl- and 2 - Acyl- benzoates and Related Esters By K. Bowden * and G. R. Taylor , Department of Chemistry , University of Essex , Colchester Rate coefficients have been measured for the alkaline ...
... Alkaline Hydrolysis of Methyl 2 - Aroyl- and 2 - Acyl- benzoates and Related Esters By K. Bowden * and G. R. Taylor , Department of Chemistry , University of Essex , Colchester Rate coefficients have been measured for the alkaline ...
Page 151
... hydrolysis by intramolecular catalysis . The 2 - pivaloyl TABLE 1 Rate coefficients for the alkaline hydrolysis of methyl 2- aroyl- and 2 - acyl - benzoates in 70 % ( v / v ) dioxan- water * Acyl or aroyl substnt . 1 H 2 Me 3 CH.Me 4 ...
... hydrolysis by intramolecular catalysis . The 2 - pivaloyl TABLE 1 Rate coefficients for the alkaline hydrolysis of methyl 2- aroyl- and 2 - acyl - benzoates in 70 % ( v / v ) dioxan- water * Acyl or aroyl substnt . 1 H 2 Me 3 CH.Me 4 ...
Page 156
... Alkaline Hydrolysis of Methyl 3 - Benzoylacrylates By K. Bowden * and M. P. Henry , Department of Chemistry , University of Essex , Colchester Rate coefficients for the alkaline hydrolysis of a series of 3'- and 4 ' - substituted methyl ...
... Alkaline Hydrolysis of Methyl 3 - Benzoylacrylates By K. Bowden * and M. P. Henry , Department of Chemistry , University of Essex , Colchester Rate coefficients for the alkaline hydrolysis of a series of 3'- and 4 ' - substituted methyl ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values