Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 94
... amount of chloride . released is slightly less , by an amount which is probably significant experimentally . Various interpretations of the nature of this side - reaction are possible . One is that it involves electrophilic ...
... amount of chloride . released is slightly less , by an amount which is probably significant experimentally . Various interpretations of the nature of this side - reaction are possible . One is that it involves electrophilic ...
Page 185
... amount of peroxide titrated was far below the amount which would have been expected if most of the oxygen molecules absorbed were involved in peroxide bond formation . Only at high oxygen consumptions did the amount of peroxide bonds ...
... amount of peroxide titrated was far below the amount which would have been expected if most of the oxygen molecules absorbed were involved in peroxide bond formation . Only at high oxygen consumptions did the amount of peroxide bonds ...
Page 519
... amounts of acetate and trifluoroacetate groups was kno wn . The results in Table 2 show that the total yield of products falls as the amount of acetic acid present is increased . At the same time , the yield of phenyl acetate rises ...
... amounts of acetate and trifluoroacetate groups was kno wn . The results in Table 2 show that the total yield of products falls as the amount of acetic acid present is increased . At the same time , the yield of phenyl acetate rises ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
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A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values