Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 996
... anion . = The spectra reported in Table 5 have an values in the range 2.4-2.6 mT , as expected for aliphatic nitroalkane radical anions , and the remaining splitting constants are in accord with the structures ( 19 ) , formed as in ...
... anion . = The spectra reported in Table 5 have an values in the range 2.4-2.6 mT , as expected for aliphatic nitroalkane radical anions , and the remaining splitting constants are in accord with the structures ( 19 ) , formed as in ...
Page 1009
... anions are efficiently captured by nitroalkane aci - anions . The sulphite radical anion shows marked selectivity in its reactions with olefinic carbon . The splitting constants of the radicals formed by addition of the species S- • and ...
... anions are efficiently captured by nitroalkane aci - anions . The sulphite radical anion shows marked selectivity in its reactions with olefinic carbon . The splitting constants of the radicals formed by addition of the species S- • and ...
Page 1011
... anion from nitromethane , but not the corresponding adducts from the other aci - anions , shows that the first of these aci - anions competes with the sulphur - containing anions for the hydroxyl radical more effectively than the other aci ...
... anion from nitromethane , but not the corresponding adducts from the other aci - anions , shows that the first of these aci - anions competes with the sulphur - containing anions for the hydroxyl radical more effectively than the other aci ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
157 other sections not shown
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Common terms and phrases
A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values
Bibliographic information
| Title | Quarterly Journal of the Chemical Society of London, Volume 1 |
| Author | Chemical Society (Great Britain) |
| Contributor | Royal Society of Chemistry (Great Britain) |
| Published | 1971 |
| Original from | the University of Michigan |
| Digitized | 6 Jun 2011 |
| Export Citation | BiBTeX EndNote RefMan |