Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 517
... benzene , 4 - t - butylcyclohexanone- benzene , and 5a - androstan - 11 - one - benzene measured at 30 ° C and calculated for 1 : 1 complex formation 4 - t - Butylcyclohexanone - benzene 1 : 1 complex 0.045 1 mol - 1 ; VSB 92 Hz ...
... benzene , 4 - t - butylcyclohexanone- benzene , and 5a - androstan - 11 - one - benzene measured at 30 ° C and calculated for 1 : 1 complex formation 4 - t - Butylcyclohexanone - benzene 1 : 1 complex 0.045 1 mol - 1 ; VSB 92 Hz ...
Page 519
... benzene with lead tetra - acetate ( 8 x 104 mol ) in trifluoroacetic acid ( 0 · 131 mol ) Products ( mol % ) TABLE 4 Products from the oxidation of toluene with lead. Reactions of Benzene and Some Monosubstituted Derivatives .— ( a ) ...
... benzene with lead tetra - acetate ( 8 x 104 mol ) in trifluoroacetic acid ( 0 · 131 mol ) Products ( mol % ) TABLE 4 Products from the oxidation of toluene with lead. Reactions of Benzene and Some Monosubstituted Derivatives .— ( a ) ...
Page 571
... benzene 1.42126 α = 2.492 ; v = 0.71 ; 71.7 cm3 ; μD = 1.87 D 4 ' - t - Butyl - 4 - hydroxyazo- benzene in benzene cv ( OH ) = 3604 cm - 1 0.000 2.2725 1.49810 2.2736 2.2748 1.49827 0.183 2.2756 1.49834 cv ( OH ) = 3603 cm - 1 TABLE 1 ...
... benzene 1.42126 α = 2.492 ; v = 0.71 ; 71.7 cm3 ; μD = 1.87 D 4 ' - t - Butyl - 4 - hydroxyazo- benzene in benzene cv ( OH ) = 3604 cm - 1 0.000 2.2725 1.49810 2.2736 2.2748 1.49827 0.183 2.2756 1.49834 cv ( OH ) = 3603 cm - 1 TABLE 1 ...
Contents
Physical organic chemistry | 1 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
Contents iii | 16 |
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A2 mechanism absorption acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration correlation deuterium diastereomers dienamines dioxan dioxan-water electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring silver perchlorate sodium solution solvent steric steric effects structure studied substituent substituted substrate sulphuric t-butyl Table temperature Tetrahedron thiophen trans triethylborane values