Quarterly Journal of the Chemical Society of London, Volume 1 |
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Page 150
... benzoate , diphenylmethyl 2 - benzoyl- benzoate , and methyl 2 - phenylacetylbenzoate . The products of hydrolysis were analysed and found to be the anion of the benzoic acid in quantitative yield . However , an immediate pale brown ...
... benzoate , diphenylmethyl 2 - benzoyl- benzoate , and methyl 2 - phenylacetylbenzoate . The products of hydrolysis were analysed and found to be the anion of the benzoic acid in quantitative yield . However , an immediate pale brown ...
Page 155
... Benzoate 40 0.374 0.0380 0.143 50 60 0.531 0.781 0.0880 0.219 0.257 0.502 * Solubilities were reproducible to within ± 2 % . 70 1.29 0.523 0.971 the esters together with the rates of hydrolysis , we can separate out the effect of the ...
... Benzoate 40 0.374 0.0380 0.143 50 60 0.531 0.781 0.0880 0.219 0.257 0.502 * Solubilities were reproducible to within ± 2 % . 70 1.29 0.523 0.971 the esters together with the rates of hydrolysis , we can separate out the effect of the ...
Page 306
... benzoate to other solvents of o- , m- , and p - nitrobenzyl chloride , at 303 K Solubility " ( mole fraction ) 0.252 0.309 0.300 0.328 From data given in ref . 37 . TABLE 9 Relative rate coefficients for the reaction of trimethylamine ...
... benzoate to other solvents of o- , m- , and p - nitrobenzyl chloride , at 303 K Solubility " ( mole fraction ) 0.252 0.309 0.300 0.328 From data given in ref . 37 . TABLE 9 Relative rate coefficients for the reaction of trimethylamine ...
Contents
Physical organic chemistry | 1 |
Contents | 6 |
Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds Part XXIV Acid | 11 |
157 other sections not shown
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Common terms and phrases
A2 mechanism acetic acid-catalysed addition alcohol alkaline hydrolysis Amer analysis anion aqueous aromatic benzene benzoate bond bromine cal mol-1 calculated carbon atom carbonium ion carbonyl catalysis Chem Chemistry chlorine compounds concentration conjugate conjugate acid correlation deuterium diastereomers dienamines dioxan electron pairs energy entropies of activation epoxide equation esters ether ethylene exchange experimental Figure formation glycol H₂O hydrogen hydroxide hypochlorous acid indicate intramolecular isomer isotope effects k₁ k₂ ketone kinetic MeOH methanol methanolysis methiodide method methyl mixture mmHg mol-¹ molecular molecule n-pentyl n.m.r. spectra nitration nucleophilic observed obtained olefin oxidation oxygen p-xylene parameters perchloric acid Phys polar positive proton R. J. W. Le Fèvre radical rate coefficients rate constants ratio reaction constant reactivity relative resorcinol ring sodium solution solvent steric steric effects structure studied substituent substituted substrate t-butyl Table temperature Tetrahedron thiophen trans triethylborane values
Bibliographic information
| Title | Quarterly Journal of the Chemical Society of London, Volume 1 |
| Author | Chemical Society (Great Britain) |
| Contributor | Royal Society of Chemistry (Great Britain) |
| Published | 1971 |
| Original from | the University of Michigan |
| Digitized | 6 Jun 2011 |
| Export Citation | BiBTeX EndNote RefMan |